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(E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate)
In the title compound, C(20)H(25)ClN(6) (2+)·2ClO(4) (−), the organic cation is roughly planar, as shown by the dihedral angle of 3.78 (3)° between the quinazoline and chlorophenyl rings. The quinazoline ring is itself approximately planar, with an average deviation of 0.018 (4) Å. The organic cati...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344656/ https://www.ncbi.nlm.nih.gov/pubmed/22590418 http://dx.doi.org/10.1107/S1600536812018272 |
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author | Jiang, Nan Zuo, Jian Wang, Haiyan Han, Ming Zhai, Xin |
author_facet | Jiang, Nan Zuo, Jian Wang, Haiyan Han, Ming Zhai, Xin |
author_sort | Jiang, Nan |
collection | PubMed |
description | In the title compound, C(20)H(25)ClN(6) (2+)·2ClO(4) (−), the organic cation is roughly planar, as shown by the dihedral angle of 3.78 (3)° between the quinazoline and chlorophenyl rings. The quinazoline ring is itself approximately planar, with an average deviation of 0.018 (4) Å. The organic cation adopts an E configuration with respect to the C= N double bond of the hyrazinyl group. The (dimethylazaniumyl)propylamino side chain is disordered over two sets of sites with occupancies of 0.768 (10) and 0.232 (10). In the crystal, two cations and four anions are linked by strong N—H⋯O hydrogen bonds. Weak C—H⋯O hydrogen bonds exist among these aggregates. |
format | Online Article Text |
id | pubmed-3344656 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33446562012-05-15 (E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate) Jiang, Nan Zuo, Jian Wang, Haiyan Han, Ming Zhai, Xin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(25)ClN(6) (2+)·2ClO(4) (−), the organic cation is roughly planar, as shown by the dihedral angle of 3.78 (3)° between the quinazoline and chlorophenyl rings. The quinazoline ring is itself approximately planar, with an average deviation of 0.018 (4) Å. The organic cation adopts an E configuration with respect to the C= N double bond of the hyrazinyl group. The (dimethylazaniumyl)propylamino side chain is disordered over two sets of sites with occupancies of 0.768 (10) and 0.232 (10). In the crystal, two cations and four anions are linked by strong N—H⋯O hydrogen bonds. Weak C—H⋯O hydrogen bonds exist among these aggregates. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344656/ /pubmed/22590418 http://dx.doi.org/10.1107/S1600536812018272 Text en © Jiang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jiang, Nan Zuo, Jian Wang, Haiyan Han, Ming Zhai, Xin (E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate) |
title | (E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate) |
title_full | (E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate) |
title_fullStr | (E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate) |
title_full_unstemmed | (E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate) |
title_short | (E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate) |
title_sort | (e)-2-[2-(4-chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344656/ https://www.ncbi.nlm.nih.gov/pubmed/22590418 http://dx.doi.org/10.1107/S1600536812018272 |
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