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(E)-2-[2-(4-Chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate)

In the title compound, C(20)H(25)ClN(6) (2+)·2ClO(4) (−), the organic cation is roughly planar, as shown by the dihedral angle of 3.78 (3)° between the quinazoline and chloro­phenyl rings. The quinazoline ring is itself approximately planar, with an average deviation of 0.018 (4) Å. The organic cati...

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Detalles Bibliográficos
Autores principales: Jiang, Nan, Zuo, Jian, Wang, Haiyan, Han, Ming, Zhai, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344656/
https://www.ncbi.nlm.nih.gov/pubmed/22590418
http://dx.doi.org/10.1107/S1600536812018272
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author Jiang, Nan
Zuo, Jian
Wang, Haiyan
Han, Ming
Zhai, Xin
author_facet Jiang, Nan
Zuo, Jian
Wang, Haiyan
Han, Ming
Zhai, Xin
author_sort Jiang, Nan
collection PubMed
description In the title compound, C(20)H(25)ClN(6) (2+)·2ClO(4) (−), the organic cation is roughly planar, as shown by the dihedral angle of 3.78 (3)° between the quinazoline and chloro­phenyl rings. The quinazoline ring is itself approximately planar, with an average deviation of 0.018 (4) Å. The organic cation adopts an E configuration with respect to the C= N double bond of the hyrazinyl group. The (dimethyl­aza­nium­yl)propyl­amino side chain is disordered over two sets of sites with occupancies of 0.768 (10) and 0.232 (10). In the crystal, two cations and four anions are linked by strong N—H⋯O hydrogen bonds. Weak C—H⋯O hydrogen bonds exist among these aggregates.
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spelling pubmed-33446562012-05-15 (E)-2-[2-(4-Chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate) Jiang, Nan Zuo, Jian Wang, Haiyan Han, Ming Zhai, Xin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(25)ClN(6) (2+)·2ClO(4) (−), the organic cation is roughly planar, as shown by the dihedral angle of 3.78 (3)° between the quinazoline and chloro­phenyl rings. The quinazoline ring is itself approximately planar, with an average deviation of 0.018 (4) Å. The organic cation adopts an E configuration with respect to the C= N double bond of the hyrazinyl group. The (dimethyl­aza­nium­yl)propyl­amino side chain is disordered over two sets of sites with occupancies of 0.768 (10) and 0.232 (10). In the crystal, two cations and four anions are linked by strong N—H⋯O hydrogen bonds. Weak C—H⋯O hydrogen bonds exist among these aggregates. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344656/ /pubmed/22590418 http://dx.doi.org/10.1107/S1600536812018272 Text en © Jiang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jiang, Nan
Zuo, Jian
Wang, Haiyan
Han, Ming
Zhai, Xin
(E)-2-[2-(4-Chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate)
title (E)-2-[2-(4-Chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate)
title_full (E)-2-[2-(4-Chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate)
title_fullStr (E)-2-[2-(4-Chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate)
title_full_unstemmed (E)-2-[2-(4-Chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate)
title_short (E)-2-[2-(4-Chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate)
title_sort (e)-2-[2-(4-chloro­benzyl­idene)hydrazin-1-yl]-4-{[3-(dimethyl­aza­nium­yl)prop­yl]amino}­quinazolin-1-ium bis­(perchlorate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344656/
https://www.ncbi.nlm.nih.gov/pubmed/22590418
http://dx.doi.org/10.1107/S1600536812018272
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