Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate

In the title compound, C(31)H(26)O(6), the five-membered ring of the indane unit adopts a slight envelope conformation with the flap atom displaced by 1.38 (14) Å. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(9) ring motif. In the crystal,...

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Detalles Bibliográficos
Autores principales: Lakshmanan, D., Murugavel, S., Kannan, D., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344660/
https://www.ncbi.nlm.nih.gov/pubmed/22590422
http://dx.doi.org/10.1107/S1600536812017965
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author Lakshmanan, D.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_facet Lakshmanan, D.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_sort Lakshmanan, D.
collection PubMed
description In the title compound, C(31)H(26)O(6), the five-membered ring of the indane unit adopts a slight envelope conformation with the flap atom displaced by 1.38 (14) Å. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(9) ring motif. In the crystal, pairs of C—H⋯O hydrogen bonds link centrosymmetrically related mol­ecules into dimers, generating R (2) (2)(22) ring motifs. The crystal packing is further stabilized by C—H⋯π inter­actions.
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spelling pubmed-33446602012-05-15 Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate Lakshmanan, D. Murugavel, S. Kannan, D. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(26)O(6), the five-membered ring of the indane unit adopts a slight envelope conformation with the flap atom displaced by 1.38 (14) Å. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(9) ring motif. In the crystal, pairs of C—H⋯O hydrogen bonds link centrosymmetrically related mol­ecules into dimers, generating R (2) (2)(22) ring motifs. The crystal packing is further stabilized by C—H⋯π inter­actions. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344660/ /pubmed/22590422 http://dx.doi.org/10.1107/S1600536812017965 Text en © Lakshmanan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lakshmanan, D.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate
title Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate
title_full Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate
title_fullStr Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate
title_full_unstemmed Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate
title_short Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate
title_sort methyl (2e)-2-({2-[(2e)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344660/
https://www.ncbi.nlm.nih.gov/pubmed/22590422
http://dx.doi.org/10.1107/S1600536812017965
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AT murugavels methyl2e222e2benzylidene3methoxy3oxopropyl13dioxoindan2ylmethyl3phenylprop2enoate
AT kannand methyl2e222e2benzylidene3methoxy3oxopropyl13dioxoindan2ylmethyl3phenylprop2enoate
AT bakthadossm methyl2e222e2benzylidene3methoxy3oxopropyl13dioxoindan2ylmethyl3phenylprop2enoate

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