N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate

The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol­ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°. The amide groups of neighbouring mol­ecules are con...

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Detalles Bibliográficos
Autores principales: Berger, Matthias, Bats, Jan W., Auner, Norbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344661/
https://www.ncbi.nlm.nih.gov/pubmed/22590423
http://dx.doi.org/10.1107/S1600536812017527
Descripción
Sumario:The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol­ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°. The amide groups of neighbouring mol­ecules are connected by N—H⋯O hydrogen bonds, forming 2(1) helical chains propagating along [001]. Mol­ecules are also connected by weak inter­molecular C—H⋯O hydrogen bonds, forming 6(1) helices.

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