N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate

The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol­ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°. The amide groups of neighbouring mol­ecules are con...

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Detalles Bibliográficos
Autores principales: Berger, Matthias, Bats, Jan W., Auner, Norbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344661/
https://www.ncbi.nlm.nih.gov/pubmed/22590423
http://dx.doi.org/10.1107/S1600536812017527
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author Berger, Matthias
Bats, Jan W.
Auner, Norbert
author_facet Berger, Matthias
Bats, Jan W.
Auner, Norbert
author_sort Berger, Matthias
collection PubMed
description The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol­ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°. The amide groups of neighbouring mol­ecules are connected by N—H⋯O hydrogen bonds, forming 2(1) helical chains propagating along [001]. Mol­ecules are also connected by weak inter­molecular C—H⋯O hydrogen bonds, forming 6(1) helices.
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spelling pubmed-33446612012-05-15 N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate Berger, Matthias Bats, Jan W. Auner, Norbert Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol­ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°. The amide groups of neighbouring mol­ecules are connected by N—H⋯O hydrogen bonds, forming 2(1) helical chains propagating along [001]. Mol­ecules are also connected by weak inter­molecular C—H⋯O hydrogen bonds, forming 6(1) helices. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344661/ /pubmed/22590423 http://dx.doi.org/10.1107/S1600536812017527 Text en © Berger et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Berger, Matthias
Bats, Jan W.
Auner, Norbert
N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate
title N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate
title_full N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate
title_fullStr N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate
title_full_unstemmed N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate
title_short N-(2,6-Diisopropyl­phen­yl)formamide toluene 0.33-solvate
title_sort n-(2,6-diisopropyl­phen­yl)formamide toluene 0.33-solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344661/
https://www.ncbi.nlm.nih.gov/pubmed/22590423
http://dx.doi.org/10.1107/S1600536812017527
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