(6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate

In the title compound, C(16)H(17)NO(3)S(2), the 2H-chromene ring is close to being planar [maximum deviation = 0.034 (2) Å] and the pyrrolidine ring is twisted about the C—C bond opposite the N atom. The dihedral angle between the ring-system planes is 75.24 (16)° and an intra­molecular C—H⋯S inter­...

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Autores principales: Mahabaleshwaraiah, N. M., Kumar, K. Mahesh, Kotresh, O., Al-eryani, Waleed Fadl Ali, Devarajegowda, H. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344662/
https://www.ncbi.nlm.nih.gov/pubmed/22590424
http://dx.doi.org/10.1107/S1600536812017953
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author Mahabaleshwaraiah, N. M.
Kumar, K. Mahesh
Kotresh, O.
Al-eryani, Waleed Fadl Ali
Devarajegowda, H. C.
author_facet Mahabaleshwaraiah, N. M.
Kumar, K. Mahesh
Kotresh, O.
Al-eryani, Waleed Fadl Ali
Devarajegowda, H. C.
author_sort Mahabaleshwaraiah, N. M.
collection PubMed
description In the title compound, C(16)H(17)NO(3)S(2), the 2H-chromene ring is close to being planar [maximum deviation = 0.034 (2) Å] and the pyrrolidine ring is twisted about the C—C bond opposite the N atom. The dihedral angle between the ring-system planes is 75.24 (16)° and an intra­molecular C—H⋯S inter­action occurs. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and the packing also exhibits π–π inter­actions, with a distance of 3.6106 (13) Å between the centroids of the benzene rings of neighbouring mol­ecules.
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spelling pubmed-33446622012-05-15 (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate Mahabaleshwaraiah, N. M. Kumar, K. Mahesh Kotresh, O. Al-eryani, Waleed Fadl Ali Devarajegowda, H. C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(17)NO(3)S(2), the 2H-chromene ring is close to being planar [maximum deviation = 0.034 (2) Å] and the pyrrolidine ring is twisted about the C—C bond opposite the N atom. The dihedral angle between the ring-system planes is 75.24 (16)° and an intra­molecular C—H⋯S inter­action occurs. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and the packing also exhibits π–π inter­actions, with a distance of 3.6106 (13) Å between the centroids of the benzene rings of neighbouring mol­ecules. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344662/ /pubmed/22590424 http://dx.doi.org/10.1107/S1600536812017953 Text en © Mahabaleshwaraiah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mahabaleshwaraiah, N. M.
Kumar, K. Mahesh
Kotresh, O.
Al-eryani, Waleed Fadl Ali
Devarajegowda, H. C.
(6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_full (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_fullStr (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_full_unstemmed (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_short (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_sort (6-meth­oxy-2-oxo-2h-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344662/
https://www.ncbi.nlm.nih.gov/pubmed/22590424
http://dx.doi.org/10.1107/S1600536812017953
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