[(3aS,5aR,8aR,8bS)-2,2,7,7-Tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (R)-N-(1-phenyl­eth­yl)sulfamate

In the title compound, C(20)H(29)NO(8)S, the two five-membered rings adopt envelope conformations (with an O atom at the flap in each case), while the six-membered pyran ring displays a twist-boat conformation. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into a supra­molecular chai...

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Detalles Bibliográficos
Autores principales: Xie, Meng, Shen, Si-Si, Chen, Bao-Feng, Sha, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344676/
https://www.ncbi.nlm.nih.gov/pubmed/22590438
http://dx.doi.org/10.1107/S1600536812016704
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author Xie, Meng
Shen, Si-Si
Chen, Bao-Feng
Sha, Yu
author_facet Xie, Meng
Shen, Si-Si
Chen, Bao-Feng
Sha, Yu
author_sort Xie, Meng
collection PubMed
description In the title compound, C(20)H(29)NO(8)S, the two five-membered rings adopt envelope conformations (with an O atom at the flap in each case), while the six-membered pyran ring displays a twist-boat conformation. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into a supra­molecular chain running along the a axis.
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spelling pubmed-33446762012-05-15 [(3aS,5aR,8aR,8bS)-2,2,7,7-Tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (R)-N-(1-phenyl­eth­yl)sulfamate Xie, Meng Shen, Si-Si Chen, Bao-Feng Sha, Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(29)NO(8)S, the two five-membered rings adopt envelope conformations (with an O atom at the flap in each case), while the six-membered pyran ring displays a twist-boat conformation. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into a supra­molecular chain running along the a axis. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344676/ /pubmed/22590438 http://dx.doi.org/10.1107/S1600536812016704 Text en © Xie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xie, Meng
Shen, Si-Si
Chen, Bao-Feng
Sha, Yu
[(3aS,5aR,8aR,8bS)-2,2,7,7-Tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (R)-N-(1-phenyl­eth­yl)sulfamate
title [(3aS,5aR,8aR,8bS)-2,2,7,7-Tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (R)-N-(1-phenyl­eth­yl)sulfamate
title_full [(3aS,5aR,8aR,8bS)-2,2,7,7-Tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (R)-N-(1-phenyl­eth­yl)sulfamate
title_fullStr [(3aS,5aR,8aR,8bS)-2,2,7,7-Tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (R)-N-(1-phenyl­eth­yl)sulfamate
title_full_unstemmed [(3aS,5aR,8aR,8bS)-2,2,7,7-Tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (R)-N-(1-phenyl­eth­yl)sulfamate
title_short [(3aS,5aR,8aR,8bS)-2,2,7,7-Tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (R)-N-(1-phenyl­eth­yl)sulfamate
title_sort [(3as,5ar,8ar,8bs)-2,2,7,7-tetra­methyl­tetra­hydro-3ah-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-3a-yl]methyl (r)-n-(1-phenyl­eth­yl)sulfamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344676/
https://www.ncbi.nlm.nih.gov/pubmed/22590438
http://dx.doi.org/10.1107/S1600536812016704
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