Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study

Kinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in...

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Autores principales: Giridhar Reddy, P., Ramesh, K., Shylaja, S., Rajanna, K. C., Kandlikar, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Scientific World Journal 2012
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3361256/
https://www.ncbi.nlm.nih.gov/pubmed/22654610
http://dx.doi.org/10.1100/2012/456516
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author Giridhar Reddy, P.
Ramesh, K.
Shylaja, S.
Rajanna, K. C.
Kandlikar, S.
author_facet Giridhar Reddy, P.
Ramesh, K.
Shylaja, S.
Rajanna, K. C.
Kandlikar, S.
author_sort Giridhar Reddy, P.
collection PubMed
description Kinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in catalyzed as well as uncatalyzed reactions. However, the order of [ketone] changed from unity to a fractional one in the presence of Ru (III). On the basis of kinetic features, the probable mechanisms are discussed and individual rate parameters evaluated.
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spelling pubmed-33612562012-05-31 Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study Giridhar Reddy, P. Ramesh, K. Shylaja, S. Rajanna, K. C. Kandlikar, S. ScientificWorldJournal Research Article Kinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in catalyzed as well as uncatalyzed reactions. However, the order of [ketone] changed from unity to a fractional one in the presence of Ru (III). On the basis of kinetic features, the probable mechanisms are discussed and individual rate parameters evaluated. The Scientific World Journal 2012-04-30 /pmc/articles/PMC3361256/ /pubmed/22654610 http://dx.doi.org/10.1100/2012/456516 Text en Copyright © 2012 P. Giridhar Reddy et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Giridhar Reddy, P.
Ramesh, K.
Shylaja, S.
Rajanna, K. C.
Kandlikar, S.
Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study
title Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study
title_full Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study
title_fullStr Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study
title_full_unstemmed Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study
title_short Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study
title_sort ru (iii) catalyzed oxidation of aliphatic ketones by n-bromosuccinimide in aqueous acetic acid: a kinetic study
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3361256/
https://www.ncbi.nlm.nih.gov/pubmed/22654610
http://dx.doi.org/10.1100/2012/456516
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