Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation

A novel and efficient method for the arylation of 2-arylbenzothiazoles is described via C–H activation. The desired C(Ar)–C(Ar) bond formation proceeded efficiently with good functional-group tolerance and high regioselectivity. Proposed mechanism for the arylation of 2-arylbenzothiazole is depicted...

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Detalles Bibliográficos
Autores principales: Ding, Qiuping, Ji, Huafang, Wang, Dan, Lin, Yuqing, Yu, Weihua, Peng, Yiyuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier Sequoia 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3363328/
https://www.ncbi.nlm.nih.gov/pubmed/22807586
http://dx.doi.org/10.1016/j.jorganchem.2012.03.030
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author Ding, Qiuping
Ji, Huafang
Wang, Dan
Lin, Yuqing
Yu, Weihua
Peng, Yiyuan
author_facet Ding, Qiuping
Ji, Huafang
Wang, Dan
Lin, Yuqing
Yu, Weihua
Peng, Yiyuan
author_sort Ding, Qiuping
collection PubMed
description A novel and efficient method for the arylation of 2-arylbenzothiazoles is described via C–H activation. The desired C(Ar)–C(Ar) bond formation proceeded efficiently with good functional-group tolerance and high regioselectivity. Proposed mechanism for the arylation of 2-arylbenzothiazole is depicted.
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spelling pubmed-33633282012-07-15 Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation Ding, Qiuping Ji, Huafang Wang, Dan Lin, Yuqing Yu, Weihua Peng, Yiyuan J Organomet Chem Article A novel and efficient method for the arylation of 2-arylbenzothiazoles is described via C–H activation. The desired C(Ar)–C(Ar) bond formation proceeded efficiently with good functional-group tolerance and high regioselectivity. Proposed mechanism for the arylation of 2-arylbenzothiazole is depicted. Elsevier Sequoia 2012-07-15 /pmc/articles/PMC3363328/ /pubmed/22807586 http://dx.doi.org/10.1016/j.jorganchem.2012.03.030 Text en © 2012 Elsevier B.V. https://creativecommons.org/licenses/by-nc-nd/3.0/ Open Access under CC BY-NC-ND 3.0 (https://creativecommons.org/licenses/by-nc-nd/3.0/) license
spellingShingle Article
Ding, Qiuping
Ji, Huafang
Wang, Dan
Lin, Yuqing
Yu, Weihua
Peng, Yiyuan
Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation
title Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation
title_full Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation
title_fullStr Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation
title_full_unstemmed Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation
title_short Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation
title_sort pd(ii)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed c–h activation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3363328/
https://www.ncbi.nlm.nih.gov/pubmed/22807586
http://dx.doi.org/10.1016/j.jorganchem.2012.03.030
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