Triple resonance for a three-level system of a chiral molecule

A new spectroscopic method of triple resonance is proposed for studying chirality of a molecule of C(1) symmetry. Each enantiomer of such a molecule is of mixed parity and thus exhibits all three a-, b-, and c-types of rotational spectra. The present study concludes, by using time-dependent perturba...

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Detalles Bibliográficos
Autor principal: HIROTA, Eizi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Japan Academy 2012
Materias:
Original Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3365249/
https://www.ncbi.nlm.nih.gov/pubmed/22450539
http://dx.doi.org/10.2183/pjab.88.120
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author HIROTA, Eizi
author_facet HIROTA, Eizi
author_sort HIROTA, Eizi
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description A new spectroscopic method of triple resonance is proposed for studying chirality of a molecule of C(1) symmetry. Each enantiomer of such a molecule is of mixed parity and thus exhibits all three a-, b-, and c-types of rotational spectra. The present study concludes, by using time-dependent perturbation theory, that the transition probability between two of the three rotational levels under triple resonance differs for different enantiomer. This result can thus be of some significance for enantiomer differentiation.
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spelling pubmed-33652492012-07-12 Triple resonance for a three-level system of a chiral molecule HIROTA, Eizi Proc Jpn Acad Ser B Phys Biol Sci Original Article A new spectroscopic method of triple resonance is proposed for studying chirality of a molecule of C(1) symmetry. Each enantiomer of such a molecule is of mixed parity and thus exhibits all three a-, b-, and c-types of rotational spectra. The present study concludes, by using time-dependent perturbation theory, that the transition probability between two of the three rotational levels under triple resonance differs for different enantiomer. This result can thus be of some significance for enantiomer differentiation. The Japan Academy 2012-03-09 /pmc/articles/PMC3365249/ /pubmed/22450539 http://dx.doi.org/10.2183/pjab.88.120 Text en © 2012 The Japan Academy This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Original Article
HIROTA, Eizi
Triple resonance for a three-level system of a chiral molecule
title Triple resonance for a three-level system of a chiral molecule
title_full Triple resonance for a three-level system of a chiral molecule
title_fullStr Triple resonance for a three-level system of a chiral molecule
title_full_unstemmed Triple resonance for a three-level system of a chiral molecule
title_short Triple resonance for a three-level system of a chiral molecule
title_sort triple resonance for a three-level system of a chiral molecule
topic Original Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3365249/
https://www.ncbi.nlm.nih.gov/pubmed/22450539
http://dx.doi.org/10.2183/pjab.88.120
work_keys_str_mv AT hirotaeizi tripleresonanceforathreelevelsystemofachiralmolecule

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