Bis[hexa­amminecobalt(III)] penta­chloride nitrate

The title compound, [Co(NH(3))(6)](2)Cl(5)(NO(3)), was obtained under hydro­thermal conditions. The asymmetric unit contains three Co(3+) ions, one lying on an inversion center and the other two located at 2/m positions. All Co(3+) ions are six-coordinated by NH(3) mol­ecules, forming [Co(NH(3))(6)]...

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Detalles Bibliográficos
Autores principales: Wu, Qihui, Du, Chunyu, Lv, Yang, Chen, Guoliang, Pan, Qinhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379055/
https://www.ncbi.nlm.nih.gov/pubmed/22719276
http://dx.doi.org/10.1107/S1600536812021332
Descripción
Sumario:The title compound, [Co(NH(3))(6)](2)Cl(5)(NO(3)), was obtained under hydro­thermal conditions. The asymmetric unit contains three Co(3+) ions, one lying on an inversion center and the other two located at 2/m positions. All Co(3+) ions are six-coordinated by NH(3) mol­ecules, forming [Co(NH(3))(6)](3+) octahedra, with Co—N distances in the range 1.945 (4)–1.967 (3) Å. The nitrate N atom and one of the O atoms lie at a mirror plane. Among the Cl(−) anions, one lies in a general position, one on a twofold axis and two on a mirror plane. N—H⋯O and N—H⋯Cl hydrogen bonds link the cations and anions into a three-dimensional network.

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