Bis[hexa­amminecobalt(III)] penta­chloride nitrate

The title compound, [Co(NH(3))(6)](2)Cl(5)(NO(3)), was obtained under hydro­thermal conditions. The asymmetric unit contains three Co(3+) ions, one lying on an inversion center and the other two located at 2/m positions. All Co(3+) ions are six-coordinated by NH(3) mol­ecules, forming [Co(NH(3))(6)]...

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Autores principales: Wu, Qihui, Du, Chunyu, Lv, Yang, Chen, Guoliang, Pan, Qinhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379055/
https://www.ncbi.nlm.nih.gov/pubmed/22719276
http://dx.doi.org/10.1107/S1600536812021332
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author Wu, Qihui
Du, Chunyu
Lv, Yang
Chen, Guoliang
Pan, Qinhe
author_facet Wu, Qihui
Du, Chunyu
Lv, Yang
Chen, Guoliang
Pan, Qinhe
author_sort Wu, Qihui
collection PubMed
description The title compound, [Co(NH(3))(6)](2)Cl(5)(NO(3)), was obtained under hydro­thermal conditions. The asymmetric unit contains three Co(3+) ions, one lying on an inversion center and the other two located at 2/m positions. All Co(3+) ions are six-coordinated by NH(3) mol­ecules, forming [Co(NH(3))(6)](3+) octahedra, with Co—N distances in the range 1.945 (4)–1.967 (3) Å. The nitrate N atom and one of the O atoms lie at a mirror plane. Among the Cl(−) anions, one lies in a general position, one on a twofold axis and two on a mirror plane. N—H⋯O and N—H⋯Cl hydrogen bonds link the cations and anions into a three-dimensional network.
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spelling pubmed-33790552012-06-20 Bis[hexa­amminecobalt(III)] penta­chloride nitrate Wu, Qihui Du, Chunyu Lv, Yang Chen, Guoliang Pan, Qinhe Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, [Co(NH(3))(6)](2)Cl(5)(NO(3)), was obtained under hydro­thermal conditions. The asymmetric unit contains three Co(3+) ions, one lying on an inversion center and the other two located at 2/m positions. All Co(3+) ions are six-coordinated by NH(3) mol­ecules, forming [Co(NH(3))(6)](3+) octahedra, with Co—N distances in the range 1.945 (4)–1.967 (3) Å. The nitrate N atom and one of the O atoms lie at a mirror plane. Among the Cl(−) anions, one lies in a general position, one on a twofold axis and two on a mirror plane. N—H⋯O and N—H⋯Cl hydrogen bonds link the cations and anions into a three-dimensional network. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379055/ /pubmed/22719276 http://dx.doi.org/10.1107/S1600536812021332 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Wu, Qihui
Du, Chunyu
Lv, Yang
Chen, Guoliang
Pan, Qinhe
Bis[hexa­amminecobalt(III)] penta­chloride nitrate
title Bis[hexa­amminecobalt(III)] penta­chloride nitrate
title_full Bis[hexa­amminecobalt(III)] penta­chloride nitrate
title_fullStr Bis[hexa­amminecobalt(III)] penta­chloride nitrate
title_full_unstemmed Bis[hexa­amminecobalt(III)] penta­chloride nitrate
title_short Bis[hexa­amminecobalt(III)] penta­chloride nitrate
title_sort bis[hexa­amminecobalt(iii)] penta­chloride nitrate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379055/
https://www.ncbi.nlm.nih.gov/pubmed/22719276
http://dx.doi.org/10.1107/S1600536812021332
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AT lvyang bishexaamminecobaltiiipentachloridenitrate
AT chenguoliang bishexaamminecobaltiiipentachloridenitrate
AT panqinhe bishexaamminecobaltiiipentachloridenitrate

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