KMg(0.09)Fe(1.91)(PO(4))(2)

KMg(0.09)Fe(1.91)(PO(4))(2), potassium [iron(II)/magnesium] iron(III) bis(orthophosphate), is a solid solution derived from compounds with general formula KM (II)Fe(PO(4))(2) (M (II) = Fe, Cu), in which the Mg atoms substitute Fe atoms only in the octa­hedrally surrounded sites. The framework of the...

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Detalles Bibliográficos
Autores principales: Yatskin, Michael M., Zatovsky, Igor V., Baumer, Vyacheslav N., Ogorodnyk, Ivan V., Slobodyanik, Nikolay S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379059/
https://www.ncbi.nlm.nih.gov/pubmed/22719280
http://dx.doi.org/10.1107/S1600536812023975
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author Yatskin, Michael M.
Zatovsky, Igor V.
Baumer, Vyacheslav N.
Ogorodnyk, Ivan V.
Slobodyanik, Nikolay S.
author_facet Yatskin, Michael M.
Zatovsky, Igor V.
Baumer, Vyacheslav N.
Ogorodnyk, Ivan V.
Slobodyanik, Nikolay S.
author_sort Yatskin, Michael M.
collection PubMed
description KMg(0.09)Fe(1.91)(PO(4))(2), potassium [iron(II)/magnesium] iron(III) bis(orthophosphate), is a solid solution derived from compounds with general formula KM (II)Fe(PO(4))(2) (M (II) = Fe, Cu), in which the Mg atoms substitute Fe atoms only in the octa­hedrally surrounded sites. The framework of the structure is built up from [FeO(5)] trigonal bipyramids and [MO(6)] (M = (Fe, Mg) octa­hedra sharing corners and edges and connected by two types of bridging PO(4) tetra­hedra. The K(+) cations are nine-coordinated and are situated in channels running along [101].
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spelling pubmed-33790592012-06-20 KMg(0.09)Fe(1.91)(PO(4))(2) Yatskin, Michael M. Zatovsky, Igor V. Baumer, Vyacheslav N. Ogorodnyk, Ivan V. Slobodyanik, Nikolay S. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers KMg(0.09)Fe(1.91)(PO(4))(2), potassium [iron(II)/magnesium] iron(III) bis(orthophosphate), is a solid solution derived from compounds with general formula KM (II)Fe(PO(4))(2) (M (II) = Fe, Cu), in which the Mg atoms substitute Fe atoms only in the octa­hedrally surrounded sites. The framework of the structure is built up from [FeO(5)] trigonal bipyramids and [MO(6)] (M = (Fe, Mg) octa­hedra sharing corners and edges and connected by two types of bridging PO(4) tetra­hedra. The K(+) cations are nine-coordinated and are situated in channels running along [101]. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379059/ /pubmed/22719280 http://dx.doi.org/10.1107/S1600536812023975 Text en © Yatskin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Yatskin, Michael M.
Zatovsky, Igor V.
Baumer, Vyacheslav N.
Ogorodnyk, Ivan V.
Slobodyanik, Nikolay S.
KMg(0.09)Fe(1.91)(PO(4))(2)
title KMg(0.09)Fe(1.91)(PO(4))(2)
title_full KMg(0.09)Fe(1.91)(PO(4))(2)
title_fullStr KMg(0.09)Fe(1.91)(PO(4))(2)
title_full_unstemmed KMg(0.09)Fe(1.91)(PO(4))(2)
title_short KMg(0.09)Fe(1.91)(PO(4))(2)
title_sort kmg(0.09)fe(1.91)(po(4))(2)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379059/
https://www.ncbi.nlm.nih.gov/pubmed/22719280
http://dx.doi.org/10.1107/S1600536812023975
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