Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate

In the title compound, [Co(NO(3))(C(9)H(11)N(3))(2)]Cl·3H(2)O, the Co(II) atom is coordinated by four N atoms from two chelating 2-(2-amino­eth­yl)-1H-benzimidazole ligands and two O atoms from one nitrate anion in a distorted octa­hedral coordination environment. In the crystal, N—H⋯Cl, N—H⋯O, O—H⋯...

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Detalles Bibliográficos
Autores principales: Zhao, Jing, Zhang, Heng, Zhu, Guoyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379060/
https://www.ncbi.nlm.nih.gov/pubmed/22719281
http://dx.doi.org/10.1107/S1600536812018612
Descripción
Sumario:In the title compound, [Co(NO(3))(C(9)H(11)N(3))(2)]Cl·3H(2)O, the Co(II) atom is coordinated by four N atoms from two chelating 2-(2-amino­eth­yl)-1H-benzimidazole ligands and two O atoms from one nitrate anion in a distorted octa­hedral coordination environment. In the crystal, N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds link the complex cations, chloride anions and solvent water mol­ecules into a three-dimensional network. π–π inter­actions between the imidazole and benzene rings and between the benzene rings are observed [centroid–centroid distances = 3.903 (3), 3.720 (3), 3.774 (3) and 3.926 (3) Å].

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