Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate

In the title compound, [Co(NO(3))(C(9)H(11)N(3))(2)]Cl·3H(2)O, the Co(II) atom is coordinated by four N atoms from two chelating 2-(2-amino­eth­yl)-1H-benzimidazole ligands and two O atoms from one nitrate anion in a distorted octa­hedral coordination environment. In the crystal, N—H⋯Cl, N—H⋯O, O—H⋯...

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Detalles Bibliográficos
Autores principales: Zhao, Jing, Zhang, Heng, Zhu, Guoyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379060/
https://www.ncbi.nlm.nih.gov/pubmed/22719281
http://dx.doi.org/10.1107/S1600536812018612
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author Zhao, Jing
Zhang, Heng
Zhu, Guoyi
author_facet Zhao, Jing
Zhang, Heng
Zhu, Guoyi
author_sort Zhao, Jing
collection PubMed
description In the title compound, [Co(NO(3))(C(9)H(11)N(3))(2)]Cl·3H(2)O, the Co(II) atom is coordinated by four N atoms from two chelating 2-(2-amino­eth­yl)-1H-benzimidazole ligands and two O atoms from one nitrate anion in a distorted octa­hedral coordination environment. In the crystal, N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds link the complex cations, chloride anions and solvent water mol­ecules into a three-dimensional network. π–π inter­actions between the imidazole and benzene rings and between the benzene rings are observed [centroid–centroid distances = 3.903 (3), 3.720 (3), 3.774 (3) and 3.926 (3) Å].
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spelling pubmed-33790602012-06-20 Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate Zhao, Jing Zhang, Heng Zhu, Guoyi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NO(3))(C(9)H(11)N(3))(2)]Cl·3H(2)O, the Co(II) atom is coordinated by four N atoms from two chelating 2-(2-amino­eth­yl)-1H-benzimidazole ligands and two O atoms from one nitrate anion in a distorted octa­hedral coordination environment. In the crystal, N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds link the complex cations, chloride anions and solvent water mol­ecules into a three-dimensional network. π–π inter­actions between the imidazole and benzene rings and between the benzene rings are observed [centroid–centroid distances = 3.903 (3), 3.720 (3), 3.774 (3) and 3.926 (3) Å]. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379060/ /pubmed/22719281 http://dx.doi.org/10.1107/S1600536812018612 Text en © Zhao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Jing
Zhang, Heng
Zhu, Guoyi
Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate
title Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate
title_full Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate
title_fullStr Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate
title_full_unstemmed Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate
title_short Bis[2-(2-amino­eth­yl)-1H-benzimidazole-κ(2) N (2),N (3)](nitrato-κ(2) O,O′)cobalt(II) chloride trihydrate
title_sort bis[2-(2-amino­eth­yl)-1h-benzimidazole-κ(2) n (2),n (3)](nitrato-κ(2) o,o′)cobalt(ii) chloride trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379060/
https://www.ncbi.nlm.nih.gov/pubmed/22719281
http://dx.doi.org/10.1107/S1600536812018612
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AT zhangheng bis22aminoethyl1hbenzimidazolek2n2n3nitratok2oocobaltiichloridetrihydrate
AT zhuguoyi bis22aminoethyl1hbenzimidazolek2n2n3nitratok2oocobaltiichloridetrihydrate

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