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Bis(2,2′-bipyridyl-κ(2) N,N′)dichlorido­rhodium(III) perchlorate

The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted o...

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Autores principales: Dikhtiarenko, Alla, Torre-Fernández, Laura, García-Granda, Santiago, García, José R., Gimeno, José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379061/
https://www.ncbi.nlm.nih.gov/pubmed/22719282
http://dx.doi.org/10.1107/S1600536812018685
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author Dikhtiarenko, Alla
Torre-Fernández, Laura
García-Granda, Santiago
García, José R.
Gimeno, José
author_facet Dikhtiarenko, Alla
Torre-Fernández, Laura
García-Granda, Santiago
García, José R.
Gimeno, José
author_sort Dikhtiarenko, Alla
collection PubMed
description The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted octa­hedral environment. The Cl ligands are cis. Two intramolecular C—H⋯Cl hydrogen bonds occur in the cationic complex . In the crystal, mol­ecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions. An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3).
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spelling pubmed-33790612012-06-20 Bis(2,2′-bipyridyl-κ(2) N,N′)dichlorido­rhodium(III) perchlorate Dikhtiarenko, Alla Torre-Fernández, Laura García-Granda, Santiago García, José R. Gimeno, José Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted octa­hedral environment. The Cl ligands are cis. Two intramolecular C—H⋯Cl hydrogen bonds occur in the cationic complex . In the crystal, mol­ecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions. An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3). International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379061/ /pubmed/22719282 http://dx.doi.org/10.1107/S1600536812018685 Text en © Dikhtiarenko et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dikhtiarenko, Alla
Torre-Fernández, Laura
García-Granda, Santiago
García, José R.
Gimeno, José
Bis(2,2′-bipyridyl-κ(2) N,N′)dichlorido­rhodium(III) perchlorate
title Bis(2,2′-bipyridyl-κ(2) N,N′)dichlorido­rhodium(III) perchlorate
title_full Bis(2,2′-bipyridyl-κ(2) N,N′)dichlorido­rhodium(III) perchlorate
title_fullStr Bis(2,2′-bipyridyl-κ(2) N,N′)dichlorido­rhodium(III) perchlorate
title_full_unstemmed Bis(2,2′-bipyridyl-κ(2) N,N′)dichlorido­rhodium(III) perchlorate
title_short Bis(2,2′-bipyridyl-κ(2) N,N′)dichlorido­rhodium(III) perchlorate
title_sort bis(2,2′-bipyridyl-κ(2) n,n′)dichlorido­rhodium(iii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379061/
https://www.ncbi.nlm.nih.gov/pubmed/22719282
http://dx.doi.org/10.1107/S1600536812018685
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