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Bis(2,2′-bipyridyl-κ(2) N,N′)dichloridorhodium(III) perchlorate
The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted o...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379061/ https://www.ncbi.nlm.nih.gov/pubmed/22719282 http://dx.doi.org/10.1107/S1600536812018685 |
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author | Dikhtiarenko, Alla Torre-Fernández, Laura García-Granda, Santiago García, José R. Gimeno, José |
author_facet | Dikhtiarenko, Alla Torre-Fernández, Laura García-Granda, Santiago García, José R. Gimeno, José |
author_sort | Dikhtiarenko, Alla |
collection | PubMed |
description | The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted octahedral environment. The Cl ligands are cis. Two intramolecular C—H⋯Cl hydrogen bonds occur in the cationic complex . In the crystal, molecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions. An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3). |
format | Online Article Text |
id | pubmed-3379061 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33790612012-06-20 Bis(2,2′-bipyridyl-κ(2) N,N′)dichloridorhodium(III) perchlorate Dikhtiarenko, Alla Torre-Fernández, Laura García-Granda, Santiago García, José R. Gimeno, José Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted octahedral environment. The Cl ligands are cis. Two intramolecular C—H⋯Cl hydrogen bonds occur in the cationic complex . In the crystal, molecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions. An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3). International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379061/ /pubmed/22719282 http://dx.doi.org/10.1107/S1600536812018685 Text en © Dikhtiarenko et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dikhtiarenko, Alla Torre-Fernández, Laura García-Granda, Santiago García, José R. Gimeno, José Bis(2,2′-bipyridyl-κ(2) N,N′)dichloridorhodium(III) perchlorate |
title | Bis(2,2′-bipyridyl-κ(2)
N,N′)dichloridorhodium(III) perchlorate |
title_full | Bis(2,2′-bipyridyl-κ(2)
N,N′)dichloridorhodium(III) perchlorate |
title_fullStr | Bis(2,2′-bipyridyl-κ(2)
N,N′)dichloridorhodium(III) perchlorate |
title_full_unstemmed | Bis(2,2′-bipyridyl-κ(2)
N,N′)dichloridorhodium(III) perchlorate |
title_short | Bis(2,2′-bipyridyl-κ(2)
N,N′)dichloridorhodium(III) perchlorate |
title_sort | bis(2,2′-bipyridyl-κ(2)
n,n′)dichloridorhodium(iii) perchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379061/ https://www.ncbi.nlm.nih.gov/pubmed/22719282 http://dx.doi.org/10.1107/S1600536812018685 |
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