catena-Poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) N:N′] 4-hy­droxy-3-sulfonato­benzoate monohydrate]

The two independent Cd(II) atoms in the polymeric title compound, [Cd(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)O(6)S)·H(2)O, lie on twofold rotation axes, and each is coordinated by four water mol­ecules and the N atoms of two 4,4′-bipyridine mol­ecules in an octa­hedral geometry. Bridging gives rise to ch...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379062/
https://www.ncbi.nlm.nih.gov/pubmed/22719283
http://dx.doi.org/10.1107/S1600536812018727
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author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description The two independent Cd(II) atoms in the polymeric title compound, [Cd(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)O(6)S)·H(2)O, lie on twofold rotation axes, and each is coordinated by four water mol­ecules and the N atoms of two 4,4′-bipyridine mol­ecules in an octa­hedral geometry. Bridging gives rise to chains along [101] and [-101]. The 4-hy­droxy-3-sulfonato­benzoate dianions are not connected to the Cd(II) atoms, but form hydrogen bonds to the coordinated water mol­ecules as well as the lattice water mol­ecule, generating a three-dimensional network.
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spelling pubmed-33790622012-06-20 catena-Poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) N:N′] 4-hy­droxy-3-sulfonato­benzoate monohydrate] Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The two independent Cd(II) atoms in the polymeric title compound, [Cd(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)O(6)S)·H(2)O, lie on twofold rotation axes, and each is coordinated by four water mol­ecules and the N atoms of two 4,4′-bipyridine mol­ecules in an octa­hedral geometry. Bridging gives rise to chains along [101] and [-101]. The 4-hy­droxy-3-sulfonato­benzoate dianions are not connected to the Cd(II) atoms, but form hydrogen bonds to the coordinated water mol­ecules as well as the lattice water mol­ecule, generating a three-dimensional network. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379062/ /pubmed/22719283 http://dx.doi.org/10.1107/S1600536812018727 Text en © Gao and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
catena-Poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) N:N′] 4-hy­droxy-3-sulfonato­benzoate monohydrate]
title catena-Poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) N:N′] 4-hy­droxy-3-sulfonato­benzoate monohydrate]
title_full catena-Poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) N:N′] 4-hy­droxy-3-sulfonato­benzoate monohydrate]
title_fullStr catena-Poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) N:N′] 4-hy­droxy-3-sulfonato­benzoate monohydrate]
title_full_unstemmed catena-Poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) N:N′] 4-hy­droxy-3-sulfonato­benzoate monohydrate]
title_short catena-Poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) N:N′] 4-hy­droxy-3-sulfonato­benzoate monohydrate]
title_sort catena-poly[[(tetra­aqua­cadmium)-μ-4,4′-bipyridine-κ(2) n:n′] 4-hy­droxy-3-sulfonato­benzoate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379062/
https://www.ncbi.nlm.nih.gov/pubmed/22719283
http://dx.doi.org/10.1107/S1600536812018727
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AT ngseikweng catenapolytetraaquacadmiumm44bipyridinek2nn4hydroxy3sulfonatobenzoatemonohydrate

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