Bis(2-trifluoro­methyl-1H-benzimidazol-3-ium) tetra­chloridomercurate dihydrate

In the title compound, (C(8)H(6)F(3)N(2))(2)[HgCl(4)]·2H(2)O, the Hg(II) cation is coordinated by four Cl(−) anions in a distorted tetra­hedral geometry. In the crystal, the 2-trifluoro­methyl-1H-benzimidazolium cations link to the [HgCl(4)](2−) complex anions and lattice water mol­ecules via N—H⋯Cl...

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Autor principal: Liu, Ming-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379063/
https://www.ncbi.nlm.nih.gov/pubmed/22719284
http://dx.doi.org/10.1107/S1600536812018855
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author Liu, Ming-Liang
author_facet Liu, Ming-Liang
author_sort Liu, Ming-Liang
collection PubMed
description In the title compound, (C(8)H(6)F(3)N(2))(2)[HgCl(4)]·2H(2)O, the Hg(II) cation is coordinated by four Cl(−) anions in a distorted tetra­hedral geometry. In the crystal, the 2-trifluoro­methyl-1H-benzimidazolium cations link to the [HgCl(4)](2−) complex anions and lattice water mol­ecules via N—H⋯Cl and N—H⋯O hydrogen bonds, and the lattice water mol­ecules further link to the Hg complex anion and the organic cations via O—H⋯Cl and O—H⋯F hydrogen bonding. One of the trifluoro­methyl groups is disordered over two orientations in a 0.59 (4):0.41 (4) ratio.
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spelling pubmed-33790632012-06-20 Bis(2-trifluoro­methyl-1H-benzimidazol-3-ium) tetra­chloridomercurate dihydrate Liu, Ming-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(6)F(3)N(2))(2)[HgCl(4)]·2H(2)O, the Hg(II) cation is coordinated by four Cl(−) anions in a distorted tetra­hedral geometry. In the crystal, the 2-trifluoro­methyl-1H-benzimidazolium cations link to the [HgCl(4)](2−) complex anions and lattice water mol­ecules via N—H⋯Cl and N—H⋯O hydrogen bonds, and the lattice water mol­ecules further link to the Hg complex anion and the organic cations via O—H⋯Cl and O—H⋯F hydrogen bonding. One of the trifluoro­methyl groups is disordered over two orientations in a 0.59 (4):0.41 (4) ratio. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379063/ /pubmed/22719284 http://dx.doi.org/10.1107/S1600536812018855 Text en © Ming-Liang Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ming-Liang
Bis(2-trifluoro­methyl-1H-benzimidazol-3-ium) tetra­chloridomercurate dihydrate
title Bis(2-trifluoro­methyl-1H-benzimidazol-3-ium) tetra­chloridomercurate dihydrate
title_full Bis(2-trifluoro­methyl-1H-benzimidazol-3-ium) tetra­chloridomercurate dihydrate
title_fullStr Bis(2-trifluoro­methyl-1H-benzimidazol-3-ium) tetra­chloridomercurate dihydrate
title_full_unstemmed Bis(2-trifluoro­methyl-1H-benzimidazol-3-ium) tetra­chloridomercurate dihydrate
title_short Bis(2-trifluoro­methyl-1H-benzimidazol-3-ium) tetra­chloridomercurate dihydrate
title_sort bis(2-trifluoro­methyl-1h-benzimidazol-3-ium) tetra­chloridomercurate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379063/
https://www.ncbi.nlm.nih.gov/pubmed/22719284
http://dx.doi.org/10.1107/S1600536812018855
work_keys_str_mv AT liumingliang bis2trifluoromethyl1hbenzimidazol3iumtetrachloridomercuratedihydrate

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