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Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4) N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate
The asymmetric unit of the title complex, [Sb(C(44)H(28)N(4))Cl(2)][Sb(2)Cl(8)](0.5)·CH(2)Cl(2), is composed of a Sb(V) complex cation wherein the Sb atom is hexacoordinated by four N atoms of the pyrrole rings of the tetraphenylporphyrinate (TPP) ligands and two chloride ions, a half di-μ-chlori...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379064/ https://www.ncbi.nlm.nih.gov/pubmed/22719285 http://dx.doi.org/10.1107/S1600536812018351 |
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author | Soury, Raoudha Belkhiria, Mohamed Sahah Nasri, Habib Parvez, Masood |
author_facet | Soury, Raoudha Belkhiria, Mohamed Sahah Nasri, Habib Parvez, Masood |
author_sort | Soury, Raoudha |
collection | PubMed |
description | The asymmetric unit of the title complex, [Sb(C(44)H(28)N(4))Cl(2)][Sb(2)Cl(8)](0.5)·CH(2)Cl(2), is composed of a Sb(V) complex cation wherein the Sb atom is hexacoordinated by four N atoms of the pyrrole rings of the tetraphenylporphyrinate (TPP) ligands and two chloride ions, a half di-μ-chlorido-bis[trichloridoantimonate(III)] counter-anion and a dichloromethane solvent molecule. In the cation, the average Sb—N distance is 2.066 (2) Å, while the Sb—Cl distances are 2.3410 (11) and 2.3639 (12) Å. The central unit of the cation, SbN(4)C(20), is far from being planar, with deviations of atoms from the least-squares plane ranging from −0.110 (4) to 0.124 (4) Å. The Sb—Cl distances in the anion, which is located about an inversion center, lie in the wide range 2.3715 (13)–2.7489 (13) Å, the longest distances being between the Sb and bridging Cl atoms. The crystal structure is stabilized by intermolecular C—H⋯Cl interactions involving the cations, the anions and the solvent molecules. The solvent molecule is disordered over two orientations in a 0.901 (13):0.099 (13) ratio. |
format | Online Article Text |
id | pubmed-3379064 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33790642012-06-20 Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4) N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate Soury, Raoudha Belkhiria, Mohamed Sahah Nasri, Habib Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Sb(C(44)H(28)N(4))Cl(2)][Sb(2)Cl(8)](0.5)·CH(2)Cl(2), is composed of a Sb(V) complex cation wherein the Sb atom is hexacoordinated by four N atoms of the pyrrole rings of the tetraphenylporphyrinate (TPP) ligands and two chloride ions, a half di-μ-chlorido-bis[trichloridoantimonate(III)] counter-anion and a dichloromethane solvent molecule. In the cation, the average Sb—N distance is 2.066 (2) Å, while the Sb—Cl distances are 2.3410 (11) and 2.3639 (12) Å. The central unit of the cation, SbN(4)C(20), is far from being planar, with deviations of atoms from the least-squares plane ranging from −0.110 (4) to 0.124 (4) Å. The Sb—Cl distances in the anion, which is located about an inversion center, lie in the wide range 2.3715 (13)–2.7489 (13) Å, the longest distances being between the Sb and bridging Cl atoms. The crystal structure is stabilized by intermolecular C—H⋯Cl interactions involving the cations, the anions and the solvent molecules. The solvent molecule is disordered over two orientations in a 0.901 (13):0.099 (13) ratio. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379064/ /pubmed/22719285 http://dx.doi.org/10.1107/S1600536812018351 Text en © Soury et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Soury, Raoudha Belkhiria, Mohamed Sahah Nasri, Habib Parvez, Masood Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4) N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
title | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
title_full | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
title_fullStr | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
title_full_unstemmed | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
title_short | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
title_sort | dichlorido(5,10,15,20-tetraphenylporphyrinato-κ(4)
n)antimony(v) hemi{di-μ-chlorido-bis[trichloridoantimonate(iii)]} dichloromethane monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379064/ https://www.ncbi.nlm.nih.gov/pubmed/22719285 http://dx.doi.org/10.1107/S1600536812018351 |
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