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Dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)anti­mony(V) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(III)]} dichloro­methane monosolvate

The asymmetric unit of the title complex, [Sb(C(44)H(28)N(4))Cl(2)][Sb(2)Cl(8)](0.5)·CH(2)Cl(2), is composed of a Sb(V) complex cation wherein the Sb atom is hexa­coordinated by four N atoms of the pyrrole rings of the tetra­phenyl­porphyrinate (TPP) ligands and two chloride ions, a half di-μ-chlori...

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Autores principales: Soury, Raoudha, Belkhiria, Mohamed Sahah, Nasri, Habib, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379064/
https://www.ncbi.nlm.nih.gov/pubmed/22719285
http://dx.doi.org/10.1107/S1600536812018351
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author Soury, Raoudha
Belkhiria, Mohamed Sahah
Nasri, Habib
Parvez, Masood
author_facet Soury, Raoudha
Belkhiria, Mohamed Sahah
Nasri, Habib
Parvez, Masood
author_sort Soury, Raoudha
collection PubMed
description The asymmetric unit of the title complex, [Sb(C(44)H(28)N(4))Cl(2)][Sb(2)Cl(8)](0.5)·CH(2)Cl(2), is composed of a Sb(V) complex cation wherein the Sb atom is hexa­coordinated by four N atoms of the pyrrole rings of the tetra­phenyl­porphyrinate (TPP) ligands and two chloride ions, a half di-μ-chlorido-bis­[trichloridoanti­monate(III)] counter-anion and a dichloro­methane solvent mol­ecule. In the cation, the average Sb—N distance is 2.066 (2) Å, while the Sb—Cl distances are 2.3410 (11) and 2.3639 (12) Å. The central unit of the cation, SbN(4)C(20), is far from being planar, with deviations of atoms from the least-squares plane ranging from −0.110 (4) to 0.124 (4) Å. The Sb—Cl distances in the anion, which is located about an inversion center, lie in the wide range 2.3715 (13)–2.7489 (13) Å, the longest distances being between the Sb and bridging Cl atoms. The crystal structure is stabilized by inter­molecular C—H⋯Cl inter­actions involving the cations, the anions and the solvent mol­ecules. The solvent mol­ecule is disordered over two orientations in a 0.901 (13):0.099 (13) ratio.
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spelling pubmed-33790642012-06-20 Dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)anti­mony(V) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(III)]} dichloro­methane monosolvate Soury, Raoudha Belkhiria, Mohamed Sahah Nasri, Habib Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Sb(C(44)H(28)N(4))Cl(2)][Sb(2)Cl(8)](0.5)·CH(2)Cl(2), is composed of a Sb(V) complex cation wherein the Sb atom is hexa­coordinated by four N atoms of the pyrrole rings of the tetra­phenyl­porphyrinate (TPP) ligands and two chloride ions, a half di-μ-chlorido-bis­[trichloridoanti­monate(III)] counter-anion and a dichloro­methane solvent mol­ecule. In the cation, the average Sb—N distance is 2.066 (2) Å, while the Sb—Cl distances are 2.3410 (11) and 2.3639 (12) Å. The central unit of the cation, SbN(4)C(20), is far from being planar, with deviations of atoms from the least-squares plane ranging from −0.110 (4) to 0.124 (4) Å. The Sb—Cl distances in the anion, which is located about an inversion center, lie in the wide range 2.3715 (13)–2.7489 (13) Å, the longest distances being between the Sb and bridging Cl atoms. The crystal structure is stabilized by inter­molecular C—H⋯Cl inter­actions involving the cations, the anions and the solvent mol­ecules. The solvent mol­ecule is disordered over two orientations in a 0.901 (13):0.099 (13) ratio. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379064/ /pubmed/22719285 http://dx.doi.org/10.1107/S1600536812018351 Text en © Soury et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Soury, Raoudha
Belkhiria, Mohamed Sahah
Nasri, Habib
Parvez, Masood
Dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)anti­mony(V) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(III)]} dichloro­methane monosolvate
title Dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)anti­mony(V) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(III)]} dichloro­methane monosolvate
title_full Dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)anti­mony(V) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(III)]} dichloro­methane monosolvate
title_fullStr Dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)anti­mony(V) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(III)]} dichloro­methane monosolvate
title_full_unstemmed Dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)anti­mony(V) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(III)]} dichloro­methane monosolvate
title_short Dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)anti­mony(V) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(III)]} dichloro­methane monosolvate
title_sort dichlorido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)anti­mony(v) hemi{di-μ-chlorido-bis­[trichloridoanti­monate(iii)]} dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379064/
https://www.ncbi.nlm.nih.gov/pubmed/22719285
http://dx.doi.org/10.1107/S1600536812018351
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AT belkhiriamohamedsahah dichlorido5101520tetraphenylporphyrinatok4nantimonyvhemidimchloridobistrichloridoantimonateiiidichloromethanemonosolvate
AT nasrihabib dichlorido5101520tetraphenylporphyrinatok4nantimonyvhemidimchloridobistrichloridoantimonateiiidichloromethanemonosolvate
AT parvezmasood dichlorido5101520tetraphenylporphyrinatok4nantimonyvhemidimchloridobistrichloridoantimonateiiidichloromethanemonosolvate