Cargando…
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2) O (3):O (1)] sesquihydrate]
The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two w...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379067/ https://www.ncbi.nlm.nih.gov/pubmed/22719288 http://dx.doi.org/10.1107/S1600536812018740 |
| _version_ | 1782236118365765632 |
|---|---|
| author | Fang, Xiang-Qian Gao, Shan Ng, Seik Weng |
| author_facet | Fang, Xiang-Qian Gao, Shan Ng, Seik Weng |
| author_sort | Fang, Xiang-Qian |
| collection | PubMed |
| description | The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in an overall octahedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3379067 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33790672012-06-20 catena-Poly[[[diaqua(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2) O (3):O (1)] sesquihydrate] Fang, Xiang-Qian Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in an overall octahedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379067/ /pubmed/22719288 http://dx.doi.org/10.1107/S1600536812018740 Text en © Fang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fang, Xiang-Qian Gao, Shan Ng, Seik Weng catena-Poly[[[diaqua(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2) O (3):O (1)] sesquihydrate] |
| title |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2)
O
(3):O
(1)] sesquihydrate] |
| title_full |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2)
O
(3):O
(1)] sesquihydrate] |
| title_fullStr |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2)
O
(3):O
(1)] sesquihydrate] |
| title_full_unstemmed |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2)
O
(3):O
(1)] sesquihydrate] |
| title_short |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2)
O
(3):O
(1)] sesquihydrate] |
| title_sort | catena-poly[[[diaqua(1,10-phenanthroline-κ(2)
n,n′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ(2)
o
(3):o
(1)] sesquihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379067/ https://www.ncbi.nlm.nih.gov/pubmed/22719288 http://dx.doi.org/10.1107/S1600536812018740 |
| work_keys_str_mv | AT fangxiangqian catenapolydiaqua110phenanthrolinek2nnzincm4hydroxy3sulfonatobenzoatok2o3o1sesquihydrate AT gaoshan catenapolydiaqua110phenanthrolinek2nnzincm4hydroxy3sulfonatobenzoatok2o3o1sesquihydrate AT ngseikweng catenapolydiaqua110phenanthrolinek2nnzincm4hydroxy3sulfonatobenzoatok2o3o1sesquihydrate |