catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido]

In the title compound, [PbBr(2)(C(14)H(12)N(2))](n), the Pb(II) atom lies on a twofold rotation axis. The N-heterocycle-chelated Pb(II) atom exists in a distorted octa­hedral geometry owing to two long Pb⋯Br inter­actions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along th...

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Detalles Bibliográficos
Autores principales: Sabour, Behrous, Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379072/
https://www.ncbi.nlm.nih.gov/pubmed/22719293
http://dx.doi.org/10.1107/S160053681201940X
Descripción
Sumario:In the title compound, [PbBr(2)(C(14)H(12)N(2))](n), the Pb(II) atom lies on a twofold rotation axis. The N-heterocycle-chelated Pb(II) atom exists in a distorted octa­hedral geometry owing to two long Pb⋯Br inter­actions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along the c axis. The lone pair is stereochemically inactive.

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