catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido]

In the title compound, [PbBr(2)(C(14)H(12)N(2))](n), the Pb(II) atom lies on a twofold rotation axis. The N-heterocycle-chelated Pb(II) atom exists in a distorted octa­hedral geometry owing to two long Pb⋯Br inter­actions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along th...

Descripción completa

Detalles Bibliográficos
Autores principales: Sabour, Behrous, Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379072/
https://www.ncbi.nlm.nih.gov/pubmed/22719293
http://dx.doi.org/10.1107/S160053681201940X
_version_ 1782236119522344960
author Sabour, Behrous
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Sabour, Behrous
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Sabour, Behrous
collection PubMed
description In the title compound, [PbBr(2)(C(14)H(12)N(2))](n), the Pb(II) atom lies on a twofold rotation axis. The N-heterocycle-chelated Pb(II) atom exists in a distorted octa­hedral geometry owing to two long Pb⋯Br inter­actions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along the c axis. The lone pair is stereochemically inactive.
format Online
Article
Text
id pubmed-3379072
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33790722012-06-20 catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido] Sabour, Behrous Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PbBr(2)(C(14)H(12)N(2))](n), the Pb(II) atom lies on a twofold rotation axis. The N-heterocycle-chelated Pb(II) atom exists in a distorted octa­hedral geometry owing to two long Pb⋯Br inter­actions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along the c axis. The lone pair is stereochemically inactive. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379072/ /pubmed/22719293 http://dx.doi.org/10.1107/S160053681201940X Text en © Sabour et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sabour, Behrous
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido]
title catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido]
title_full catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido]
title_fullStr catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido]
title_full_unstemmed catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido]
title_short catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-bromido]
title_sort catena-poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)lead(ii)]-di-μ-bromido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379072/
https://www.ncbi.nlm.nih.gov/pubmed/22719293
http://dx.doi.org/10.1107/S160053681201940X
work_keys_str_mv AT sabourbehrous catenapoly29dimethyl110phenanthrolinek2nnleadiidimbromido
AT najafiezzatollah catenapoly29dimethyl110phenanthrolinek2nnleadiidimbromido
AT aminimostafam catenapoly29dimethyl110phenanthrolinek2nnleadiidimbromido
AT ngseikweng catenapoly29dimethyl110phenanthrolinek2nnleadiidimbromido

Ejemplares similares