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(μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis[triaqua(glycinato-κ(2) N,O)copper(II)]
In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalenedisulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms. The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octahedron owing...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379073/ https://www.ncbi.nlm.nih.gov/pubmed/22719294 http://dx.doi.org/10.1107/S1600536812019332 |
| Sumario: | In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalenedisulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms. The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octahedron owing to a long Cu—O(sulfonate) bond [2.636 (2) Å]. In the crystal, extensive N—H⋯O and O—H⋯O hydrogen bonds link adjacent molecules into a three-dimensional network |
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