(μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis­[triaqua­(glycinato-κ(2) N,O)copper(II)]

In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalene­disulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms. The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octa­hedron owing...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379073/
https://www.ncbi.nlm.nih.gov/pubmed/22719294
http://dx.doi.org/10.1107/S1600536812019332
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author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalene­disulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms. The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octa­hedron owing to a long Cu—O(sulfonate) bond [2.636 (2) Å]. In the crystal, extensive N—H⋯O and O—H⋯O hydrogen bonds link adjacent mol­ecules into a three-dimensional network
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spelling pubmed-33790732012-06-20 (μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis­[triaqua­(glycinato-κ(2) N,O)copper(II)] Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalene­disulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms. The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octa­hedron owing to a long Cu—O(sulfonate) bond [2.636 (2) Å]. In the crystal, extensive N—H⋯O and O—H⋯O hydrogen bonds link adjacent mol­ecules into a three-dimensional network International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379073/ /pubmed/22719294 http://dx.doi.org/10.1107/S1600536812019332 Text en © Gao and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
(μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis­[triaqua­(glycinato-κ(2) N,O)copper(II)]
title (μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis­[triaqua­(glycinato-κ(2) N,O)copper(II)]
title_full (μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis­[triaqua­(glycinato-κ(2) N,O)copper(II)]
title_fullStr (μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis­[triaqua­(glycinato-κ(2) N,O)copper(II)]
title_full_unstemmed (μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis­[triaqua­(glycinato-κ(2) N,O)copper(II)]
title_short (μ-Naphthalene-1,5-disulfonato-κ(2) O (1):O (5))bis­[triaqua­(glycinato-κ(2) N,O)copper(II)]
title_sort (μ-naphthalene-1,5-disulfonato-κ(2) o (1):o (5))bis­[triaqua­(glycinato-κ(2) n,o)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379073/
https://www.ncbi.nlm.nih.gov/pubmed/22719294
http://dx.doi.org/10.1107/S1600536812019332
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AT ngseikweng mnaphthalene15disulfonatok2o1o5bistriaquaglycinatok2nocopperii

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