Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate

The Ag(I) atom in the title compound, [Ag(NO(3))(C(10)H(20)N(4))(2)]·C(2)H(5)OH·H(2)O, is coordinated by the N atoms of two N-heterocycles [N—Ag—N = 151.5 (1)°]; the approximately linear coordination geometry is distorted into a T-shaped geometry owing to a long Ag⋯O(nitrate) bond [2.717 (4) Å]. The...

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Detalles Bibliográficos
Autores principales: Liu, Ya-Mei, Chen, Jing-Huo, Yang, Guang, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379074/
https://www.ncbi.nlm.nih.gov/pubmed/22719295
http://dx.doi.org/10.1107/S1600536812019058
Descripción
Sumario:The Ag(I) atom in the title compound, [Ag(NO(3))(C(10)H(20)N(4))(2)]·C(2)H(5)OH·H(2)O, is coordinated by the N atoms of two N-heterocycles [N—Ag—N = 151.5 (1)°]; the approximately linear coordination geometry is distorted into a T-shaped geometry owing to a long Ag⋯O(nitrate) bond [2.717 (4) Å]. The N atoms of the N-heterocycles that are not involved in coordination point towards the lattice water mol­ecule, which functions as a hydrogen-bond donor. The water mol­ecule itself is a hydrogen-bond acceptor towards the ethanol solvent mol­ecule. Hydrogen bonds of the type N–H⋯O give rise to a layer motif parallel to (001).

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