Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate

The Ag(I) atom in the title compound, [Ag(NO(3))(C(10)H(20)N(4))(2)]·C(2)H(5)OH·H(2)O, is coordinated by the N atoms of two N-heterocycles [N—Ag—N = 151.5 (1)°]; the approximately linear coordination geometry is distorted into a T-shaped geometry owing to a long Ag⋯O(nitrate) bond [2.717 (4) Å]. The...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Ya-Mei, Chen, Jing-Huo, Yang, Guang, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379074/
https://www.ncbi.nlm.nih.gov/pubmed/22719295
http://dx.doi.org/10.1107/S1600536812019058
_version_ 1782236119969038336
author Liu, Ya-Mei
Chen, Jing-Huo
Yang, Guang
Ng, Seik Weng
author_facet Liu, Ya-Mei
Chen, Jing-Huo
Yang, Guang
Ng, Seik Weng
author_sort Liu, Ya-Mei
collection PubMed
description The Ag(I) atom in the title compound, [Ag(NO(3))(C(10)H(20)N(4))(2)]·C(2)H(5)OH·H(2)O, is coordinated by the N atoms of two N-heterocycles [N—Ag—N = 151.5 (1)°]; the approximately linear coordination geometry is distorted into a T-shaped geometry owing to a long Ag⋯O(nitrate) bond [2.717 (4) Å]. The N atoms of the N-heterocycles that are not involved in coordination point towards the lattice water mol­ecule, which functions as a hydrogen-bond donor. The water mol­ecule itself is a hydrogen-bond acceptor towards the ethanol solvent mol­ecule. Hydrogen bonds of the type N–H⋯O give rise to a layer motif parallel to (001).
format Online
Article
Text
id pubmed-3379074
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33790742012-06-20 Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate Liu, Ya-Mei Chen, Jing-Huo Yang, Guang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ag(I) atom in the title compound, [Ag(NO(3))(C(10)H(20)N(4))(2)]·C(2)H(5)OH·H(2)O, is coordinated by the N atoms of two N-heterocycles [N—Ag—N = 151.5 (1)°]; the approximately linear coordination geometry is distorted into a T-shaped geometry owing to a long Ag⋯O(nitrate) bond [2.717 (4) Å]. The N atoms of the N-heterocycles that are not involved in coordination point towards the lattice water mol­ecule, which functions as a hydrogen-bond donor. The water mol­ecule itself is a hydrogen-bond acceptor towards the ethanol solvent mol­ecule. Hydrogen bonds of the type N–H⋯O give rise to a layer motif parallel to (001). International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379074/ /pubmed/22719295 http://dx.doi.org/10.1107/S1600536812019058 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ya-Mei
Chen, Jing-Huo
Yang, Guang
Ng, Seik Weng
Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate
title Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate
title_full Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate
title_fullStr Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate
title_full_unstemmed Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate
title_short Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN (1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate
title_sort bis(3,5-di-tert-butyl-4h-1,2,4-triazol-4-amine-κn (1))(nitrato-κo)silver(i) ethanol monosolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379074/
https://www.ncbi.nlm.nih.gov/pubmed/22719295
http://dx.doi.org/10.1107/S1600536812019058
work_keys_str_mv AT liuyamei bis35ditertbutyl4h124triazol4aminekn1nitratokosilveriethanolmonosolvatemonohydrate
AT chenjinghuo bis35ditertbutyl4h124triazol4aminekn1nitratokosilveriethanolmonosolvatemonohydrate
AT yangguang bis35ditertbutyl4h124triazol4aminekn1nitratokosilveriethanolmonosolvatemonohydrate
AT ngseikweng bis35ditertbutyl4h124triazol4aminekn1nitratokosilveriethanolmonosolvatemonohydrate

Ejemplares similares