A triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­(thio­cyanato-κN)cobalt(II)] 1,2-bis­(pyridin-4-yl)ethene monosolvate]

In the crystal structure of the title compound, [Co(NCS)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2), the Co(II) cations are octa­hedrally coordinated by two terminally N-bonded thio­cyanate anions and four 1,2-bis­(pyridin-4-yl)ethene (bpe) ligands. The asymmetric unit consists of three crystallographica...

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Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379076/
https://www.ncbi.nlm.nih.gov/pubmed/22719297
http://dx.doi.org/10.1107/S1600536812019009
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author Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description In the crystal structure of the title compound, [Co(NCS)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2), the Co(II) cations are octa­hedrally coordinated by two terminally N-bonded thio­cyanate anions and four 1,2-bis­(pyridin-4-yl)ethene (bpe) ligands. The asymmetric unit consists of three crystallographically independent Co(II) cations, six thio­cyanate anions and six coordinating bpe ligands in general positions. Additionally, three non-coordin­ating bpe ligands are present in the asymmetric unit with two of them located on a center of inversion. The Co(II) cations are connected by the bpe ligands into layers parallel to the bc plane. The crystal investigated was non-merohedrically twinned, with a fractional contribution of 0.261 (2) for the minor domain.
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spelling pubmed-33790762012-06-20 A triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­(thio­cyanato-κN)cobalt(II)] 1,2-bis­(pyridin-4-yl)ethene monosolvate] Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Co(NCS)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2), the Co(II) cations are octa­hedrally coordinated by two terminally N-bonded thio­cyanate anions and four 1,2-bis­(pyridin-4-yl)ethene (bpe) ligands. The asymmetric unit consists of three crystallographically independent Co(II) cations, six thio­cyanate anions and six coordinating bpe ligands in general positions. Additionally, three non-coordin­ating bpe ligands are present in the asymmetric unit with two of them located on a center of inversion. The Co(II) cations are connected by the bpe ligands into layers parallel to the bc plane. The crystal investigated was non-merohedrically twinned, with a fractional contribution of 0.261 (2) for the minor domain. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379076/ /pubmed/22719297 http://dx.doi.org/10.1107/S1600536812019009 Text en © Wöhlert et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Jess, Inke
Näther, Christian
A triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­(thio­cyanato-κN)cobalt(II)] 1,2-bis­(pyridin-4-yl)ethene monosolvate]
title A triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­(thio­cyanato-κN)cobalt(II)] 1,2-bis­(pyridin-4-yl)ethene monosolvate]
title_full A triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­(thio­cyanato-κN)cobalt(II)] 1,2-bis­(pyridin-4-yl)ethene monosolvate]
title_fullStr A triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­(thio­cyanato-κN)cobalt(II)] 1,2-bis­(pyridin-4-yl)ethene monosolvate]
title_full_unstemmed A triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­(thio­cyanato-κN)cobalt(II)] 1,2-bis­(pyridin-4-yl)ethene monosolvate]
title_short A triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­(thio­cyanato-κN)cobalt(II)] 1,2-bis­(pyridin-4-yl)ethene monosolvate]
title_sort triclinic polymorph of poly[[bis­[μ-1,2-bis­(pyridin-4-yl)ethene-κ(2) n:n′]bis­(thio­cyanato-κn)cobalt(ii)] 1,2-bis­(pyridin-4-yl)ethene monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379076/
https://www.ncbi.nlm.nih.gov/pubmed/22719297
http://dx.doi.org/10.1107/S1600536812019009
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