8-Hy­droxy-2-methyl­quinolinium tetra­chlorido(quinolin-8-olato-κ(2) N,O)stan­nate(IV)

The reaction of 8-hy­droxy­quinoline, 2-methyl­quinolin-8-ol and stannic chloride yields the protonated 8-hy­droxy-2-methyl­quinolinium species. In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379079/
https://www.ncbi.nlm.nih.gov/pubmed/22719300
http://dx.doi.org/10.1107/S1600536812019459
Descripción
Sumario:The reaction of 8-hy­droxy­quinoline, 2-methyl­quinolin-8-ol and stannic chloride yields the protonated 8-hy­droxy-2-methyl­quinolinium species. In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four Cl(−) anions in a distorted cis-SnNOCl(4) octa­hedral geometry. In the crystal, the cation is linked to the anion by an O—H⋯O hydrogen bond.

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