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8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2) N,O)stannate(IV)
The reaction of 8-hydroxyquinoline, 2-methylquinolin-8-ol and stannic chloride yields the protonated 8-hydroxy-2-methylquinolinium species. In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379079/ https://www.ncbi.nlm.nih.gov/pubmed/22719300 http://dx.doi.org/10.1107/S1600536812019459 |
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author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_sort | Najafi, Ezzatollah |
collection | PubMed |
description | The reaction of 8-hydroxyquinoline, 2-methylquinolin-8-ol and stannic chloride yields the protonated 8-hydroxy-2-methylquinolinium species. In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four Cl(−) anions in a distorted cis-SnNOCl(4) octahedral geometry. In the crystal, the cation is linked to the anion by an O—H⋯O hydrogen bond. |
format | Online Article Text |
id | pubmed-3379079 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33790792012-06-20 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2) N,O)stannate(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 8-hydroxyquinoline, 2-methylquinolin-8-ol and stannic chloride yields the protonated 8-hydroxy-2-methylquinolinium species. In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four Cl(−) anions in a distorted cis-SnNOCl(4) octahedral geometry. In the crystal, the cation is linked to the anion by an O—H⋯O hydrogen bond. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379079/ /pubmed/22719300 http://dx.doi.org/10.1107/S1600536812019459 Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2) N,O)stannate(IV) |
title | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2)
N,O)stannate(IV) |
title_full | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2)
N,O)stannate(IV) |
title_fullStr | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2)
N,O)stannate(IV) |
title_full_unstemmed | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2)
N,O)stannate(IV) |
title_short | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2)
N,O)stannate(IV) |
title_sort | 8-hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ(2)
n,o)stannate(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379079/ https://www.ncbi.nlm.nih.gov/pubmed/22719300 http://dx.doi.org/10.1107/S1600536812019459 |
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