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Tris(5,6-dimethyl-1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II)

The title mononuclear complex, [Ni(C(7)H(3)NO(4))(C(9)H(10)N(2))(3)], shows a central Ni(II) atom which is coordinated by two carboxyl­ate O atoms and the N atom from a pyridine-2,6-dicarboxyl­ate ligand and by three N atoms from different 5,6-dimethyl-1H-­benzimidazole ligands in a distorted octa­h...

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Detalles Bibliográficos
Autores principales: Li, Yue-Hua, Li, Feng-Feng, Liu, Xin-Hua, Zhao, Ling-Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379080/
https://www.ncbi.nlm.nih.gov/pubmed/22719301
http://dx.doi.org/10.1107/S1600536812019502
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author Li, Yue-Hua
Li, Feng-Feng
Liu, Xin-Hua
Zhao, Ling-Yan
author_facet Li, Yue-Hua
Li, Feng-Feng
Liu, Xin-Hua
Zhao, Ling-Yan
author_sort Li, Yue-Hua
collection PubMed
description The title mononuclear complex, [Ni(C(7)H(3)NO(4))(C(9)H(10)N(2))(3)], shows a central Ni(II) atom which is coordinated by two carboxyl­ate O atoms and the N atom from a pyridine-2,6-dicarboxyl­ate ligand and by three N atoms from different 5,6-dimethyl-1H-­benzimidazole ligands in a distorted octa­hedral geometry. The crystal structure shows intermolecular N—H⋯O hydrogen bonds.
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spelling pubmed-33790802012-06-20 Tris(5,6-dimethyl-1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II) Li, Yue-Hua Li, Feng-Feng Liu, Xin-Hua Zhao, Ling-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear complex, [Ni(C(7)H(3)NO(4))(C(9)H(10)N(2))(3)], shows a central Ni(II) atom which is coordinated by two carboxyl­ate O atoms and the N atom from a pyridine-2,6-dicarboxyl­ate ligand and by three N atoms from different 5,6-dimethyl-1H-­benzimidazole ligands in a distorted octa­hedral geometry. The crystal structure shows intermolecular N—H⋯O hydrogen bonds. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379080/ /pubmed/22719301 http://dx.doi.org/10.1107/S1600536812019502 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yue-Hua
Li, Feng-Feng
Liu, Xin-Hua
Zhao, Ling-Yan
Tris(5,6-dimethyl-1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II)
title Tris(5,6-dimethyl-1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II)
title_full Tris(5,6-dimethyl-1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II)
title_fullStr Tris(5,6-dimethyl-1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II)
title_full_unstemmed Tris(5,6-dimethyl-1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II)
title_short Tris(5,6-dimethyl-1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II)
title_sort tris(5,6-dimethyl-1h-benzimidazole-κn (3))(pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379080/
https://www.ncbi.nlm.nih.gov/pubmed/22719301
http://dx.doi.org/10.1107/S1600536812019502
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