10-Hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) methanol monosolvate

The reaction of 4-(dimethyl­amino)­pyridine, picolinic acid and stannic chloride yields the title monosolvated salt, (C(13)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]·CH(3)OH. The Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa­hedral geometry. The cation is linked to the methanol sol...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379083/
https://www.ncbi.nlm.nih.gov/pubmed/22719304
http://dx.doi.org/10.1107/S1600536812019605
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description The reaction of 4-(dimethyl­amino)­pyridine, picolinic acid and stannic chloride yields the title monosolvated salt, (C(13)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]·CH(3)OH. The Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa­hedral geometry. The cation is linked to the methanol solvent mol­ecule by an O—H⋯O hydrogen bond; the solvent mol­ecule itself is a hydrogen-bond donor to the uncoordinating carboxyl­ate O atom of the anion. The cations and anions are linked by weak N—H⋯Cl inter­actions, forming a chain running along the b axis.
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spelling pubmed-33790832012-06-20 10-Hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) methanol monosolvate Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 4-(dimethyl­amino)­pyridine, picolinic acid and stannic chloride yields the title monosolvated salt, (C(13)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]·CH(3)OH. The Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa­hedral geometry. The cation is linked to the methanol solvent mol­ecule by an O—H⋯O hydrogen bond; the solvent mol­ecule itself is a hydrogen-bond donor to the uncoordinating carboxyl­ate O atom of the anion. The cations and anions are linked by weak N—H⋯Cl inter­actions, forming a chain running along the b axis. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379083/ /pubmed/22719304 http://dx.doi.org/10.1107/S1600536812019605 Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
10-Hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) methanol monosolvate
title 10-Hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) methanol monosolvate
title_full 10-Hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) methanol monosolvate
title_fullStr 10-Hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) methanol monosolvate
title_full_unstemmed 10-Hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) methanol monosolvate
title_short 10-Hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) methanol monosolvate
title_sort 10-hy­droxy­benzo[h]quinolin-1-ium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) n,o)stannate(iv) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379083/
https://www.ncbi.nlm.nih.gov/pubmed/22719304
http://dx.doi.org/10.1107/S1600536812019605
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