4-(Dimethyl­amino)­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV)

The reaction of 4-(dimethyl­amino)­pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa­hedral geometry. The cation is linked to the anion by an N—H⋯O hydro...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379084/
https://www.ncbi.nlm.nih.gov/pubmed/22719305
http://dx.doi.org/10.1107/S160053681201968X
Descripción
Sumario:The reaction of 4-(dimethyl­amino)­pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa­hedral geometry. The cation is linked to the anion by an N—H⋯O hydrogen bond.

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