Cargando…
4-(Dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2) N,O)stannate(IV)
The reaction of 4-(dimethylamino)pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octahedral geometry. The cation is linked to the anion by an N—H⋯O hydro...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379084/ https://www.ncbi.nlm.nih.gov/pubmed/22719305 http://dx.doi.org/10.1107/S160053681201968X |
_version_ | 1782236122300022784 |
---|---|
author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_sort | Najafi, Ezzatollah |
collection | PubMed |
description | The reaction of 4-(dimethylamino)pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octahedral geometry. The cation is linked to the anion by an N—H⋯O hydrogen bond. |
format | Online Article Text |
id | pubmed-3379084 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33790842012-06-20 4-(Dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2) N,O)stannate(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 4-(dimethylamino)pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octahedral geometry. The cation is linked to the anion by an N—H⋯O hydrogen bond. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379084/ /pubmed/22719305 http://dx.doi.org/10.1107/S160053681201968X Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng 4-(Dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2) N,O)stannate(IV) |
title | 4-(Dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_full | 4-(Dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_fullStr | 4-(Dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_full_unstemmed | 4-(Dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_short | 4-(Dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_sort | 4-(dimethylamino)pyridinium tetrachlorido(pyridine-2-carboxylato-κ(2)
n,o)stannate(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379084/ https://www.ncbi.nlm.nih.gov/pubmed/22719305 http://dx.doi.org/10.1107/S160053681201968X |
work_keys_str_mv | AT najafiezzatollah 4dimethylaminopyridiniumtetrachloridopyridine2carboxylatok2nostannateiv AT aminimostafam 4dimethylaminopyridiniumtetrachloridopyridine2carboxylatok2nostannateiv AT ngseikweng 4dimethylaminopyridiniumtetrachloridopyridine2carboxylatok2nostannateiv |