Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II)

In the crystal structure of the title compound, [Ni(C(2)N(3))(2)(C(5)H(5)N)(4)], the Ni(II) cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni⋯Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be ref...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379085/
https://www.ncbi.nlm.nih.gov/pubmed/22719306
http://dx.doi.org/10.1107/S1600536812019691
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author Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description In the crystal structure of the title compound, [Ni(C(2)N(3))(2)(C(5)H(5)N)(4)], the Ni(II) cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni⋯Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors.
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spelling pubmed-33790852012-06-20 Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II) Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ni(C(2)N(3))(2)(C(5)H(5)N)(4)], the Ni(II) cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni⋯Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379085/ /pubmed/22719306 http://dx.doi.org/10.1107/S1600536812019691 Text en © Wöhlert et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II)
title Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II)
title_full Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II)
title_fullStr Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II)
title_full_unstemmed Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II)
title_short Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II)
title_sort bis(dicyanamido-κn)tetra­kis­(pyridine-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379085/
https://www.ncbi.nlm.nih.gov/pubmed/22719306
http://dx.doi.org/10.1107/S1600536812019691
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