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Triaqua-1κO,2κ(2) O-bis(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate
In the binuclear title compound, [Cu(2)(C(8)H(4)O(4))Cl(C(10)H(8)N(2))(2)(H(2)O)(3)]NO(3)·H(2)O, the two crystallographically independent Cu(II) ions have similar coordination environments. One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water molecule occupying the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379086/ https://www.ncbi.nlm.nih.gov/pubmed/22719307 http://dx.doi.org/10.1107/S1600536812019848 |
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author | Liu, Yang Feng, Yong-Lan Kuang, Dai-Zhi |
author_facet | Liu, Yang Feng, Yong-Lan Kuang, Dai-Zhi |
author_sort | Liu, Yang |
collection | PubMed |
description | In the binuclear title compound, [Cu(2)(C(8)H(4)O(4))Cl(C(10)H(8)N(2))(2)(H(2)O)(3)]NO(3)·H(2)O, the two crystallographically independent Cu(II) ions have similar coordination environments. One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water molecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2′-bipyridine molecule, one carboxylate O atom from a terephthalate ligand and one O atom from a water molecule. The other Cu(II) ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water molecule. An O—H⋯O and O—H⋯Cl hydrogen-bonded three-dimensional network is formed between the components. |
format | Online Article Text |
id | pubmed-3379086 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33790862012-06-20 Triaqua-1κO,2κ(2) O-bis(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate Liu, Yang Feng, Yong-Lan Kuang, Dai-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title compound, [Cu(2)(C(8)H(4)O(4))Cl(C(10)H(8)N(2))(2)(H(2)O)(3)]NO(3)·H(2)O, the two crystallographically independent Cu(II) ions have similar coordination environments. One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water molecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2′-bipyridine molecule, one carboxylate O atom from a terephthalate ligand and one O atom from a water molecule. The other Cu(II) ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water molecule. An O—H⋯O and O—H⋯Cl hydrogen-bonded three-dimensional network is formed between the components. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379086/ /pubmed/22719307 http://dx.doi.org/10.1107/S1600536812019848 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Yang Feng, Yong-Lan Kuang, Dai-Zhi Triaqua-1κO,2κ(2) O-bis(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate |
title | Triaqua-1κO,2κ(2)
O-bis(2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2)
O
(1):O
(4)-dicopper(II) nitrate monohydrate |
title_full | Triaqua-1κO,2κ(2)
O-bis(2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2)
O
(1):O
(4)-dicopper(II) nitrate monohydrate |
title_fullStr | Triaqua-1κO,2κ(2)
O-bis(2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2)
O
(1):O
(4)-dicopper(II) nitrate monohydrate |
title_full_unstemmed | Triaqua-1κO,2κ(2)
O-bis(2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2)
O
(1):O
(4)-dicopper(II) nitrate monohydrate |
title_short | Triaqua-1κO,2κ(2)
O-bis(2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2)
O
(1):O
(4)-dicopper(II) nitrate monohydrate |
title_sort | triaqua-1κo,2κ(2)
o-bis(2,2′-bipyridine)-1κ(2)
n,n′;2κ(2)
n,n′-chlorido-1κcl-μ-terephthalato-1:2κ(2)
o
(1):o
(4)-dicopper(ii) nitrate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379086/ https://www.ncbi.nlm.nih.gov/pubmed/22719307 http://dx.doi.org/10.1107/S1600536812019848 |
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