Cargando…

Triaqua-1κO,2κ(2) O-bis­(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate

In the binuclear title compound, [Cu(2)(C(8)H(4)O(4))Cl(C(10)H(8)N(2))(2)(H(2)O)(3)]NO(3)·H(2)O, the two crystallographically independent Cu(II) ions have similar coordination environments. One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water mol­ecule occupying the...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Yang, Feng, Yong-Lan, Kuang, Dai-Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379086/
https://www.ncbi.nlm.nih.gov/pubmed/22719307
http://dx.doi.org/10.1107/S1600536812019848
_version_ 1782236122764541952
author Liu, Yang
Feng, Yong-Lan
Kuang, Dai-Zhi
author_facet Liu, Yang
Feng, Yong-Lan
Kuang, Dai-Zhi
author_sort Liu, Yang
collection PubMed
description In the binuclear title compound, [Cu(2)(C(8)H(4)O(4))Cl(C(10)H(8)N(2))(2)(H(2)O)(3)]NO(3)·H(2)O, the two crystallographically independent Cu(II) ions have similar coordination environments. One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water mol­ecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2′-bipyridine mol­ecule, one carboxyl­ate O atom from a terephthalate ligand and one O atom from a water mol­ecule. The other Cu(II) ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water mol­ecule. An O—H⋯O and O—H⋯Cl hydrogen-bonded three-dimensional network is formed between the components.
format Online
Article
Text
id pubmed-3379086
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33790862012-06-20 Triaqua-1κO,2κ(2) O-bis­(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate Liu, Yang Feng, Yong-Lan Kuang, Dai-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title compound, [Cu(2)(C(8)H(4)O(4))Cl(C(10)H(8)N(2))(2)(H(2)O)(3)]NO(3)·H(2)O, the two crystallographically independent Cu(II) ions have similar coordination environments. One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water mol­ecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2′-bipyridine mol­ecule, one carboxyl­ate O atom from a terephthalate ligand and one O atom from a water mol­ecule. The other Cu(II) ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water mol­ecule. An O—H⋯O and O—H⋯Cl hydrogen-bonded three-dimensional network is formed between the components. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379086/ /pubmed/22719307 http://dx.doi.org/10.1107/S1600536812019848 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yang
Feng, Yong-Lan
Kuang, Dai-Zhi
Triaqua-1κO,2κ(2) O-bis­(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate
title Triaqua-1κO,2κ(2) O-bis­(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate
title_full Triaqua-1κO,2κ(2) O-bis­(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate
title_fullStr Triaqua-1κO,2κ(2) O-bis­(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate
title_full_unstemmed Triaqua-1κO,2κ(2) O-bis­(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate
title_short Triaqua-1κO,2κ(2) O-bis­(2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′-chlorido-1κCl-μ-terephthalato-1:2κ(2) O (1):O (4)-dicopper(II) nitrate monohydrate
title_sort triaqua-1κo,2κ(2) o-bis­(2,2′-bipyridine)-1κ(2) n,n′;2κ(2) n,n′-chlorido-1κcl-μ-terephthalato-1:2κ(2) o (1):o (4)-dicopper(ii) nitrate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379086/
https://www.ncbi.nlm.nih.gov/pubmed/22719307
http://dx.doi.org/10.1107/S1600536812019848
work_keys_str_mv AT liuyang triaqua1ko2k2obis22bipyridine1k2nn2k2nnchlorido1kclmterephthalato12k2o1o4dicopperiinitratemonohydrate
AT fengyonglan triaqua1ko2k2obis22bipyridine1k2nn2k2nnchlorido1kclmterephthalato12k2o1o4dicopperiinitratemonohydrate
AT kuangdaizhi triaqua1ko2k2obis22bipyridine1k2nn2k2nnchlorido1kclmterephthalato12k2o1o4dicopperiinitratemonohydrate