N,N′-Dibutyl-N,N,N′,N′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(III)]

The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions. The two half-cations are completed by crystallographic inversion symmetry. The Fe(III) atoms adopt fairly regular FeCl(3)O tetra­hedral geometries, although the br...

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Autores principales: Närhi, Sari M., Kostamo, Jatta, Asikkala, Janne, Oilunkaniemi, Raija, Laitinen, Risto S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379087/
https://www.ncbi.nlm.nih.gov/pubmed/22719308
http://dx.doi.org/10.1107/S1600536812019964
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author Närhi, Sari M.
Kostamo, Jatta
Asikkala, Janne
Oilunkaniemi, Raija
Laitinen, Risto S.
author_facet Närhi, Sari M.
Kostamo, Jatta
Asikkala, Janne
Oilunkaniemi, Raija
Laitinen, Risto S.
author_sort Närhi, Sari M.
collection PubMed
description The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions. The two half-cations are completed by crystallographic inversion symmetry. The Fe(III) atoms adopt fairly regular FeCl(3)O tetra­hedral geometries, although the bridging Fe—O—Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation. In the crystal, the components are linked by C—H⋯Cl and C—H⋯O inter­actions.
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spelling pubmed-33790872012-06-20 N,N′-Dibutyl-N,N,N′,N′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(III)] Närhi, Sari M. Kostamo, Jatta Asikkala, Janne Oilunkaniemi, Raija Laitinen, Risto S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions. The two half-cations are completed by crystallographic inversion symmetry. The Fe(III) atoms adopt fairly regular FeCl(3)O tetra­hedral geometries, although the bridging Fe—O—Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation. In the crystal, the components are linked by C—H⋯Cl and C—H⋯O inter­actions. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379087/ /pubmed/22719308 http://dx.doi.org/10.1107/S1600536812019964 Text en © Närhi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Närhi, Sari M.
Kostamo, Jatta
Asikkala, Janne
Oilunkaniemi, Raija
Laitinen, Risto S.
N,N′-Dibutyl-N,N,N′,N′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(III)]
title N,N′-Dibutyl-N,N,N′,N′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(III)]
title_full N,N′-Dibutyl-N,N,N′,N′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(III)]
title_fullStr N,N′-Dibutyl-N,N,N′,N′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(III)]
title_full_unstemmed N,N′-Dibutyl-N,N,N′,N′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(III)]
title_short N,N′-Dibutyl-N,N,N′,N′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(III)]
title_sort n,n′-dibutyl-n,n,n′,n′-tetra­methyl­ethane-1,2-diaminium μ-oxido-bis­[trichloridoferrate(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379087/
https://www.ncbi.nlm.nih.gov/pubmed/22719308
http://dx.doi.org/10.1107/S1600536812019964
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