Lithium bis­(2-methyl­lactato)borate monohydrate

The title compound {systematic name: poly[[aqua­lithium]-μ-3,3,8,8-tetra­methyl-1,4,6,9-tetra­oxa-5λ(4)-borataspiro­[4.4]nonane-2,7-dione]}, [Li(C(8)H(12)BO(6))(H(2)O)](n) (LiBMLB), forms a 12-membered macrocycle, which lies across a crystallographic inversion center. The lithium cations are pseudo-...

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Detalles Bibliográficos
Autores principales: Allen, Joshua L., Paillard, Elie, Boyle, Paul D., Henderson, Wesley A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379088/
https://www.ncbi.nlm.nih.gov/pubmed/22719309
http://dx.doi.org/10.1107/S1600536812017540
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author Allen, Joshua L.
Paillard, Elie
Boyle, Paul D.
Henderson, Wesley A.
author_facet Allen, Joshua L.
Paillard, Elie
Boyle, Paul D.
Henderson, Wesley A.
author_sort Allen, Joshua L.
collection PubMed
description The title compound {systematic name: poly[[aqua­lithium]-μ-3,3,8,8-tetra­methyl-1,4,6,9-tetra­oxa-5λ(4)-borataspiro­[4.4]nonane-2,7-dione]}, [Li(C(8)H(12)BO(6))(H(2)O)](n) (LiBMLB), forms a 12-membered macrocycle, which lies across a crystallographic inversion center. The lithium cations are pseudo-tetra­hedrally coordinated by three methyl­lactate ligands and a water mol­ecule. The asymmetric units couple across crystallographic inversion centers, forming the 12-membered macrocycles. These macrocycles, in turn, cross-link through the Li(+) cations, forming an infinite polymeric structure in two dimensions parallel to (101).
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spelling pubmed-33790882012-06-20 Lithium bis­(2-methyl­lactato)borate monohydrate Allen, Joshua L. Paillard, Elie Boyle, Paul D. Henderson, Wesley A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound {systematic name: poly[[aqua­lithium]-μ-3,3,8,8-tetra­methyl-1,4,6,9-tetra­oxa-5λ(4)-borataspiro­[4.4]nonane-2,7-dione]}, [Li(C(8)H(12)BO(6))(H(2)O)](n) (LiBMLB), forms a 12-membered macrocycle, which lies across a crystallographic inversion center. The lithium cations are pseudo-tetra­hedrally coordinated by three methyl­lactate ligands and a water mol­ecule. The asymmetric units couple across crystallographic inversion centers, forming the 12-membered macrocycles. These macrocycles, in turn, cross-link through the Li(+) cations, forming an infinite polymeric structure in two dimensions parallel to (101). International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379088/ /pubmed/22719309 http://dx.doi.org/10.1107/S1600536812017540 Text en © Allen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Allen, Joshua L.
Paillard, Elie
Boyle, Paul D.
Henderson, Wesley A.
Lithium bis­(2-methyl­lactato)borate monohydrate
title Lithium bis­(2-methyl­lactato)borate monohydrate
title_full Lithium bis­(2-methyl­lactato)borate monohydrate
title_fullStr Lithium bis­(2-methyl­lactato)borate monohydrate
title_full_unstemmed Lithium bis­(2-methyl­lactato)borate monohydrate
title_short Lithium bis­(2-methyl­lactato)borate monohydrate
title_sort lithium bis­(2-methyl­lactato)borate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379088/
https://www.ncbi.nlm.nih.gov/pubmed/22719309
http://dx.doi.org/10.1107/S1600536812017540
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AT paillardelie lithiumbis2methyllactatoboratemonohydrate
AT boylepauld lithiumbis2methyllactatoboratemonohydrate
AT hendersonwesleya lithiumbis2methyllactatoboratemonohydrate

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