{4,4′,6,6′-Tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)

In the title compound, [Cu(C(19)H(16)I(4)N(2)O(2))], the Cu(II) atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated Sc...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Shakarami, Tayebeh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379091/
https://www.ncbi.nlm.nih.gov/pubmed/22719312
http://dx.doi.org/10.1107/S1600536812020387
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author Kargar, Hadi
Kia, Reza
Shakarami, Tayebeh
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Shakarami, Tayebeh
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description In the title compound, [Cu(C(19)H(16)I(4)N(2)O(2))], the Cu(II) atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated Schiff base. The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)°. In the crystal, a short I⋯I [3.8766 (6) Å] contact is present and links neighbouring mol­ecules into chains propagating along the a axis.
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spelling pubmed-33790912012-06-20 {4,4′,6,6′-Tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) Kargar, Hadi Kia, Reza Shakarami, Tayebeh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(19)H(16)I(4)N(2)O(2))], the Cu(II) atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated Schiff base. The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)°. In the crystal, a short I⋯I [3.8766 (6) Å] contact is present and links neighbouring mol­ecules into chains propagating along the a axis. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379091/ /pubmed/22719312 http://dx.doi.org/10.1107/S1600536812020387 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Shakarami, Tayebeh
Tahir, Muhammad Nawaz
{4,4′,6,6′-Tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title {4,4′,6,6′-Tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_full {4,4′,6,6′-Tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_fullStr {4,4′,6,6′-Tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_full_unstemmed {4,4′,6,6′-Tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_short {4,4′,6,6′-Tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_sort {4,4′,6,6′-tetra­iodo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379091/
https://www.ncbi.nlm.nih.gov/pubmed/22719312
http://dx.doi.org/10.1107/S1600536812020387
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