{4,4′,6,6′-Tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II)

The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex. The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand. The dihedr...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379092/
https://www.ncbi.nlm.nih.gov/pubmed/22719313
http://dx.doi.org/10.1107/S1600536812020375
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author Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex. The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 23.19 (17)°. In the crystal, a short inter­molecular Br⋯Br [3.6475 (7) Å] inter­action is present.
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spelling pubmed-33790922012-06-20 {4,4′,6,6′-Tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex. The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 23.19 (17)°. In the crystal, a short inter­molecular Br⋯Br [3.6475 (7) Å] inter­action is present. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379092/ /pubmed/22719313 http://dx.doi.org/10.1107/S1600536812020375 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
{4,4′,6,6′-Tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II)
title {4,4′,6,6′-Tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II)
title_full {4,4′,6,6′-Tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II)
title_fullStr {4,4′,6,6′-Tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II)
title_full_unstemmed {4,4′,6,6′-Tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II)
title_short {4,4′,6,6′-Tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II)
title_sort {4,4′,6,6′-tetra­bromo-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379092/
https://www.ncbi.nlm.nih.gov/pubmed/22719313
http://dx.doi.org/10.1107/S1600536812020375
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