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Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN (3)}dichlorido­cadmium hexa­hydrate

In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial posi...

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Detalles Bibliográficos
Autores principales: Xie, Xin-Nian, Lu, Meng, Yuan, Juan, Yang, Huai-Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379093/
https://www.ncbi.nlm.nih.gov/pubmed/22719314
http://dx.doi.org/10.1107/S160053681202034X
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author Xie, Xin-Nian
Lu, Meng
Yuan, Juan
Yang, Huai-Xia
author_facet Xie, Xin-Nian
Lu, Meng
Yuan, Juan
Yang, Huai-Xia
author_sort Xie, Xin-Nian
collection PubMed
description In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octa­hedral environment. The two coordinating and two of the lattice water mol­ecules are also located on twofold rotation axes. In the crystal, complex mol­ecules and solvent water mol­ecules are linked through a complex inter­molecular N—H⋯O, O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen-bonding scheme into a three-dimensional network.
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spelling pubmed-33790932012-06-20 Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN (3)}dichlorido­cadmium hexa­hydrate Xie, Xin-Nian Lu, Meng Yuan, Juan Yang, Huai-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octa­hedral environment. The two coordinating and two of the lattice water mol­ecules are also located on twofold rotation axes. In the crystal, complex mol­ecules and solvent water mol­ecules are linked through a complex inter­molecular N—H⋯O, O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen-bonding scheme into a three-dimensional network. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379093/ /pubmed/22719314 http://dx.doi.org/10.1107/S160053681202034X Text en © Xie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xie, Xin-Nian
Lu, Meng
Yuan, Juan
Yang, Huai-Xia
Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN (3)}dichlorido­cadmium hexa­hydrate
title Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN (3)}dichlorido­cadmium hexa­hydrate
title_full Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN (3)}dichlorido­cadmium hexa­hydrate
title_fullStr Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN (3)}dichlorido­cadmium hexa­hydrate
title_full_unstemmed Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN (3)}dichlorido­cadmium hexa­hydrate
title_short Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN (3)}dichlorido­cadmium hexa­hydrate
title_sort diaqua­bis­{1-[(1h-benzimidazol-2-yl)meth­yl]-1h-imidazole-κn (3)}dichlorido­cadmium hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379093/
https://www.ncbi.nlm.nih.gov/pubmed/22719314
http://dx.doi.org/10.1107/S160053681202034X
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