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Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN (3)}dichloridocadmium hexahydrate
In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial posi...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379093/ https://www.ncbi.nlm.nih.gov/pubmed/22719314 http://dx.doi.org/10.1107/S160053681202034X |
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author | Xie, Xin-Nian Lu, Meng Yuan, Juan Yang, Huai-Xia |
author_facet | Xie, Xin-Nian Lu, Meng Yuan, Juan Yang, Huai-Xia |
author_sort | Xie, Xin-Nian |
collection | PubMed |
description | In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octahedral environment. The two coordinating and two of the lattice water molecules are also located on twofold rotation axes. In the crystal, complex molecules and solvent water molecules are linked through a complex intermolecular N—H⋯O, O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen-bonding scheme into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3379093 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33790932012-06-20 Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN (3)}dichloridocadmium hexahydrate Xie, Xin-Nian Lu, Meng Yuan, Juan Yang, Huai-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octahedral environment. The two coordinating and two of the lattice water molecules are also located on twofold rotation axes. In the crystal, complex molecules and solvent water molecules are linked through a complex intermolecular N—H⋯O, O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen-bonding scheme into a three-dimensional network. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379093/ /pubmed/22719314 http://dx.doi.org/10.1107/S160053681202034X Text en © Xie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xie, Xin-Nian Lu, Meng Yuan, Juan Yang, Huai-Xia Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN (3)}dichloridocadmium hexahydrate |
title | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN
(3)}dichloridocadmium hexahydrate |
title_full | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN
(3)}dichloridocadmium hexahydrate |
title_fullStr | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN
(3)}dichloridocadmium hexahydrate |
title_full_unstemmed | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN
(3)}dichloridocadmium hexahydrate |
title_short | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN
(3)}dichloridocadmium hexahydrate |
title_sort | diaquabis{1-[(1h-benzimidazol-2-yl)methyl]-1h-imidazole-κn
(3)}dichloridocadmium hexahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379093/ https://www.ncbi.nlm.nih.gov/pubmed/22719314 http://dx.doi.org/10.1107/S160053681202034X |
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