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Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4) O (1):O (1′):O (3),O (3′))bis(pyridine-κN)cobalt(II)]
In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octahedral geometry by four O atoms from benzenedicarboxylate anions and two N atoms from pyrid...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379094/ https://www.ncbi.nlm.nih.gov/pubmed/22719315 http://dx.doi.org/10.1107/S1600536812020028 |
Sumario: | In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octahedral geometry by four O atoms from benzenedicarboxylate anions and two N atoms from pyridine ligands. The benzenedicarboxylate dianions bridge the Co(II) atoms into a tape running along the b axis. C—H⋯O hydrogen bonds are observed in the tape and between the tapes. |
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