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Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4) O (1):O (1′):O (3),O (3′))bis(pyridine-κN)cobalt(II)]
In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octahedral geometry by four O atoms from benzenedicarboxylate anions and two N atoms from pyrid...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379094/ https://www.ncbi.nlm.nih.gov/pubmed/22719315 http://dx.doi.org/10.1107/S1600536812020028 |
| _version_ | 1782236124639395840 |
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| author | Xie, Fengxia Zhang, Dan Zhang, Xinxin |
| author_facet | Xie, Fengxia Zhang, Dan Zhang, Xinxin |
| author_sort | Xie, Fengxia |
| collection | PubMed |
| description | In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octahedral geometry by four O atoms from benzenedicarboxylate anions and two N atoms from pyridine ligands. The benzenedicarboxylate dianions bridge the Co(II) atoms into a tape running along the b axis. C—H⋯O hydrogen bonds are observed in the tape and between the tapes. |
| format | Online Article Text |
| id | pubmed-3379094 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33790942012-06-20 Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4) O (1):O (1′):O (3),O (3′))bis(pyridine-κN)cobalt(II)] Xie, Fengxia Zhang, Dan Zhang, Xinxin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octahedral geometry by four O atoms from benzenedicarboxylate anions and two N atoms from pyridine ligands. The benzenedicarboxylate dianions bridge the Co(II) atoms into a tape running along the b axis. C—H⋯O hydrogen bonds are observed in the tape and between the tapes. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379094/ /pubmed/22719315 http://dx.doi.org/10.1107/S1600536812020028 Text en © Xie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xie, Fengxia Zhang, Dan Zhang, Xinxin Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4) O (1):O (1′):O (3),O (3′))bis(pyridine-κN)cobalt(II)] |
| title | Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4)
O
(1):O
(1′):O
(3),O
(3′))bis(pyridine-κN)cobalt(II)] |
| title_full | Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4)
O
(1):O
(1′):O
(3),O
(3′))bis(pyridine-κN)cobalt(II)] |
| title_fullStr | Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4)
O
(1):O
(1′):O
(3),O
(3′))bis(pyridine-κN)cobalt(II)] |
| title_full_unstemmed | Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4)
O
(1):O
(1′):O
(3),O
(3′))bis(pyridine-κN)cobalt(II)] |
| title_short | Poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4)
O
(1):O
(1′):O
(3),O
(3′))bis(pyridine-κN)cobalt(II)] |
| title_sort | poly[(μ(3)-benzene-1,3-dicarboxylato-κ(4)
o
(1):o
(1′):o
(3),o
(3′))bis(pyridine-κn)cobalt(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379094/ https://www.ncbi.nlm.nih.gov/pubmed/22719315 http://dx.doi.org/10.1107/S1600536812020028 |
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