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A new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate)
The title double molecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues. The Cd(II) atom adopts a near-regular CdO(6) octahedral coordination geometry. The crystal structure can be described as an alternation of cationic and anionic layers along [010...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379097/ https://www.ncbi.nlm.nih.gov/pubmed/22719318 http://dx.doi.org/10.1107/S1600536812020089 |
| _version_ | 1782236125324115968 |
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| author | Wang, Bi-Qin Yan, Hai-Biao Fang, Ci-Jun Zhang, Zhi |
| author_facet | Wang, Bi-Qin Yan, Hai-Biao Fang, Ci-Jun Zhang, Zhi |
| author_sort | Wang, Bi-Qin |
| collection | PubMed |
| description | The title double molecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues. The Cd(II) atom adopts a near-regular CdO(6) octahedral coordination geometry. The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O—H⋯O and N—H⋯O hydrogen bonds are observed. No thermal anomalies corresponding to possible phase transitions were observed in DSC (differential scanning calorimetry) measurements and the 93 K structure is almost the same as the room-temperature structure. |
| format | Online Article Text |
| id | pubmed-3379097 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33790972012-06-20 A new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate) Wang, Bi-Qin Yan, Hai-Biao Fang, Ci-Jun Zhang, Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title double molecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues. The Cd(II) atom adopts a near-regular CdO(6) octahedral coordination geometry. The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O—H⋯O and N—H⋯O hydrogen bonds are observed. No thermal anomalies corresponding to possible phase transitions were observed in DSC (differential scanning calorimetry) measurements and the 93 K structure is almost the same as the room-temperature structure. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379097/ /pubmed/22719318 http://dx.doi.org/10.1107/S1600536812020089 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Bi-Qin Yan, Hai-Biao Fang, Ci-Jun Zhang, Zhi A new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate) |
| title | A new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate) |
| title_full | A new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate) |
| title_fullStr | A new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate) |
| title_full_unstemmed | A new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate) |
| title_short | A new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate) |
| title_sort | new dabco-templated metal sulfate: 1,4-diazoniabicyclo[2.2.2]octane hexaaquacadmium bis(sulfate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379097/ https://www.ncbi.nlm.nih.gov/pubmed/22719318 http://dx.doi.org/10.1107/S1600536812020089 |
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