Cargando…

9-Amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))ferrate(III) tetra­hydrate

The asymmetric unit of the title compound, (C(13)H(11)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O, contains a 9-amino­acridinium cation, one anionic complex and four uncoordinated water mol­ecules. In the anionic complex, the Fe(III) ion is six-coordinated by two almost perpendicular [dihedral angle = 88.78 ...

Descripción completa

Detalles Bibliográficos
Autores principales: Mirzaei, Masoud, Eshtiagh-Hosseini, Hossein, Eydizadeh, Ehsan, Yousefi, Zakieh, Molčanov, Krešimir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379098/
https://www.ncbi.nlm.nih.gov/pubmed/22719319
http://dx.doi.org/10.1107/S1600536812020247
_version_ 1782236125550608384
author Mirzaei, Masoud
Eshtiagh-Hosseini, Hossein
Eydizadeh, Ehsan
Yousefi, Zakieh
Molčanov, Krešimir
author_facet Mirzaei, Masoud
Eshtiagh-Hosseini, Hossein
Eydizadeh, Ehsan
Yousefi, Zakieh
Molčanov, Krešimir
author_sort Mirzaei, Masoud
collection PubMed
description The asymmetric unit of the title compound, (C(13)H(11)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O, contains a 9-amino­acridinium cation, one anionic complex and four uncoordinated water mol­ecules. In the anionic complex, the Fe(III) ion is six-coordinated by two almost perpendicular [dihedral angle = 88.78 (7)°] pyridine-2,6-dicarboxyl­ate ligands in a distorted octa­hedral geometry. In the crystal, anions are connected into chains along [10-1] by weak C—H⋯O inter­actions, which create ten-membered hydrogen-bonded R (2) (2)(10) rings. These chains are linked by three-membered water clusters. The final three-dimensional network is constructed by numerous inter­molecular O—H⋯O and N—H⋯O inter­actions.
format Online
Article
Text
id pubmed-3379098
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33790982012-06-20 9-Amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))ferrate(III) tetra­hydrate Mirzaei, Masoud Eshtiagh-Hosseini, Hossein Eydizadeh, Ehsan Yousefi, Zakieh Molčanov, Krešimir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(13)H(11)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O, contains a 9-amino­acridinium cation, one anionic complex and four uncoordinated water mol­ecules. In the anionic complex, the Fe(III) ion is six-coordinated by two almost perpendicular [dihedral angle = 88.78 (7)°] pyridine-2,6-dicarboxyl­ate ligands in a distorted octa­hedral geometry. In the crystal, anions are connected into chains along [10-1] by weak C—H⋯O inter­actions, which create ten-membered hydrogen-bonded R (2) (2)(10) rings. These chains are linked by three-membered water clusters. The final three-dimensional network is constructed by numerous inter­molecular O—H⋯O and N—H⋯O inter­actions. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379098/ /pubmed/22719319 http://dx.doi.org/10.1107/S1600536812020247 Text en © Mirzaei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mirzaei, Masoud
Eshtiagh-Hosseini, Hossein
Eydizadeh, Ehsan
Yousefi, Zakieh
Molčanov, Krešimir
9-Amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))ferrate(III) tetra­hydrate
title 9-Amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))ferrate(III) tetra­hydrate
title_full 9-Amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))ferrate(III) tetra­hydrate
title_fullStr 9-Amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))ferrate(III) tetra­hydrate
title_full_unstemmed 9-Amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))ferrate(III) tetra­hydrate
title_short 9-Amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))ferrate(III) tetra­hydrate
title_sort 9-amino­acridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))ferrate(iii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379098/
https://www.ncbi.nlm.nih.gov/pubmed/22719319
http://dx.doi.org/10.1107/S1600536812020247
work_keys_str_mv AT mirzaeimasoud 9aminoacridiniumbispyridine26dicarboxylatok3o2no6ferrateiiitetrahydrate
AT eshtiaghhosseinihossein 9aminoacridiniumbispyridine26dicarboxylatok3o2no6ferrateiiitetrahydrate
AT eydizadehehsan 9aminoacridiniumbispyridine26dicarboxylatok3o2no6ferrateiiitetrahydrate
AT yousefizakieh 9aminoacridiniumbispyridine26dicarboxylatok3o2no6ferrateiiitetrahydrate
AT molcanovkresimir 9aminoacridiniumbispyridine26dicarboxylatok3o2no6ferrateiiitetrahydrate