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catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)]
In the title compound, [Ni(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(2)](n), the Ni(II) atom, located on an inversion center, is ligated in an octahedral geometry by two carboxylate O atoms from two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate (L) ligands and two O atoms from water molecules in...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379099/ https://www.ncbi.nlm.nih.gov/pubmed/22719320 http://dx.doi.org/10.1107/S1600536812020259 |
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author | Gao, Ru-Qin Xia, Chao-Hui Li, Guo-Ting |
author_facet | Gao, Ru-Qin Xia, Chao-Hui Li, Guo-Ting |
author_sort | Gao, Ru-Qin |
collection | PubMed |
description | In the title compound, [Ni(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(2)](n), the Ni(II) atom, located on an inversion center, is ligated in an octahedral geometry by two carboxylate O atoms from two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate (L) ligands and two O atoms from water molecules in the equatorial plane, and two pyridine N atoms from other two L ligands at the apical sites. Two L ligands bridge pairs of metal atoms in an antiparallel manner, forming centrosymmetric dinuclear quasi-rectangular units which are linked into infinite double-stranded chains parallel to [100]. O—H⋯O hydrogen bonds between the coordinating water molecules and the carboxylate groups of the L ligand as well as interchain S⋯N interactions [2.726 (2)–3.363 (2) Å] lead to the formation of a layer structure parallel to (001). |
format | Online Article Text |
id | pubmed-3379099 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33790992012-06-20 catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)] Gao, Ru-Qin Xia, Chao-Hui Li, Guo-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(2)](n), the Ni(II) atom, located on an inversion center, is ligated in an octahedral geometry by two carboxylate O atoms from two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate (L) ligands and two O atoms from water molecules in the equatorial plane, and two pyridine N atoms from other two L ligands at the apical sites. Two L ligands bridge pairs of metal atoms in an antiparallel manner, forming centrosymmetric dinuclear quasi-rectangular units which are linked into infinite double-stranded chains parallel to [100]. O—H⋯O hydrogen bonds between the coordinating water molecules and the carboxylate groups of the L ligand as well as interchain S⋯N interactions [2.726 (2)–3.363 (2) Å] lead to the formation of a layer structure parallel to (001). International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379099/ /pubmed/22719320 http://dx.doi.org/10.1107/S1600536812020259 Text en © Gao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Ru-Qin Xia, Chao-Hui Li, Guo-Ting catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)] |
title |
catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)] |
title_full |
catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)] |
title_fullStr |
catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)] |
title_full_unstemmed |
catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)] |
title_short |
catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)] |
title_sort | catena-poly[[diaquanickel(ii)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379099/ https://www.ncbi.nlm.nih.gov/pubmed/22719320 http://dx.doi.org/10.1107/S1600536812020259 |
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