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catena-Poly[[diaqua­nickel(II)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)]

In the title compound, [Ni(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(2)](n), the Ni(II) atom, located on an inversion center, is ligated in an octa­hedral geometry by two carboxyl­ate O atoms from two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetate (L) ligands and two O atoms from water mol­ecules in...

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Autores principales: Gao, Ru-Qin, Xia, Chao-Hui, Li, Guo-Ting
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379099/
https://www.ncbi.nlm.nih.gov/pubmed/22719320
http://dx.doi.org/10.1107/S1600536812020259
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author Gao, Ru-Qin
Xia, Chao-Hui
Li, Guo-Ting
author_facet Gao, Ru-Qin
Xia, Chao-Hui
Li, Guo-Ting
author_sort Gao, Ru-Qin
collection PubMed
description In the title compound, [Ni(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(2)](n), the Ni(II) atom, located on an inversion center, is ligated in an octa­hedral geometry by two carboxyl­ate O atoms from two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetate (L) ligands and two O atoms from water mol­ecules in the equatorial plane, and two pyridine N atoms from other two L ligands at the apical sites. Two L ligands bridge pairs of metal atoms in an anti­parallel manner, forming centrosymmetric dinuclear quasi-recta­ngular units which are linked into infinite double-stranded chains parallel to [100]. O—H⋯O hydrogen bonds between the coordinating water mol­ecules and the carboxyl­ate groups of the L ligand as well as interchain S⋯N inter­actions [2.726 (2)–3.363 (2) Å] lead to the formation of a layer structure parallel to (001).
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spelling pubmed-33790992012-06-20 catena-Poly[[diaqua­nickel(II)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)] Gao, Ru-Qin Xia, Chao-Hui Li, Guo-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(2)](n), the Ni(II) atom, located on an inversion center, is ligated in an octa­hedral geometry by two carboxyl­ate O atoms from two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetate (L) ligands and two O atoms from water mol­ecules in the equatorial plane, and two pyridine N atoms from other two L ligands at the apical sites. Two L ligands bridge pairs of metal atoms in an anti­parallel manner, forming centrosymmetric dinuclear quasi-recta­ngular units which are linked into infinite double-stranded chains parallel to [100]. O—H⋯O hydrogen bonds between the coordinating water mol­ecules and the carboxyl­ate groups of the L ligand as well as interchain S⋯N inter­actions [2.726 (2)–3.363 (2) Å] lead to the formation of a layer structure parallel to (001). International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379099/ /pubmed/22719320 http://dx.doi.org/10.1107/S1600536812020259 Text en © Gao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Ru-Qin
Xia, Chao-Hui
Li, Guo-Ting
catena-Poly[[diaqua­nickel(II)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)]
title catena-Poly[[diaqua­nickel(II)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)]
title_full catena-Poly[[diaqua­nickel(II)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)]
title_fullStr catena-Poly[[diaqua­nickel(II)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)]
title_full_unstemmed catena-Poly[[diaqua­nickel(II)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)]
title_short catena-Poly[[diaqua­nickel(II)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)]
title_sort catena-poly[[diaqua­nickel(ii)]-bis­(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379099/
https://www.ncbi.nlm.nih.gov/pubmed/22719320
http://dx.doi.org/10.1107/S1600536812020259
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