Bis{N (2),N (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κN}bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)

In the title compound, [Co(NCS)(2)(C(19)H(17)N(5)O(2))(2)(CH(3)OH)(2)], the Co(II) atom lies on an inversion center and is coordinated by two isothio­cyanate N atoms, two O atoms of methanol mol­ecules and two pyridine N atoms in a slightly distorted octa­hedral environment. Inter­molecular O—H⋯O an...

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Detalles Bibliográficos
Autores principales: Yang, Guang-Rui, Ren, Juan, Li, Guo-Ting
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379100/
https://www.ncbi.nlm.nih.gov/pubmed/22719321
http://dx.doi.org/10.1107/S1600536812020326
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author Yang, Guang-Rui
Ren, Juan
Li, Guo-Ting
author_facet Yang, Guang-Rui
Ren, Juan
Li, Guo-Ting
author_sort Yang, Guang-Rui
collection PubMed
description In the title compound, [Co(NCS)(2)(C(19)H(17)N(5)O(2))(2)(CH(3)OH)(2)], the Co(II) atom lies on an inversion center and is coordinated by two isothio­cyanate N atoms, two O atoms of methanol mol­ecules and two pyridine N atoms in a slightly distorted octa­hedral environment. Inter­molecular O—H⋯O and N—H⋯N hydrogen bonds join the complex mol­ecules into layers parallel to the bc plane.
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spelling pubmed-33791002012-06-20 Bis{N (2),N (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κN}bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II) Yang, Guang-Rui Ren, Juan Li, Guo-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NCS)(2)(C(19)H(17)N(5)O(2))(2)(CH(3)OH)(2)], the Co(II) atom lies on an inversion center and is coordinated by two isothio­cyanate N atoms, two O atoms of methanol mol­ecules and two pyridine N atoms in a slightly distorted octa­hedral environment. Inter­molecular O—H⋯O and N—H⋯N hydrogen bonds join the complex mol­ecules into layers parallel to the bc plane. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379100/ /pubmed/22719321 http://dx.doi.org/10.1107/S1600536812020326 Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Guang-Rui
Ren, Juan
Li, Guo-Ting
Bis{N (2),N (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κN}bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title Bis{N (2),N (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κN}bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_full Bis{N (2),N (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κN}bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_fullStr Bis{N (2),N (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κN}bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_full_unstemmed Bis{N (2),N (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κN}bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_short Bis{N (2),N (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κN}bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_sort bis{n (2),n (6)-bis­[(pyridin-3-yl)meth­yl]pyridine-2,6-dicarboxamide-κn}bis­(methanol-κo)bis­(thio­cyanato-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379100/
https://www.ncbi.nlm.nih.gov/pubmed/22719321
http://dx.doi.org/10.1107/S1600536812020326
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