[2-Formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(II) perchlorate

In the unsymmetrical title complex, [Ni(C(20)H(23)N(4)O(4))]ClO(4), the coordination geometry for the Ni(II) atom can be described as square planar. The aromatic rings in the two ligands are almost vertical, with a dihedral angle of 85.3°. In the crystal, cations and anions are linked by weak C(N)—H...

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Detalles Bibliográficos
Autores principales: Wang, Yang, Mao, Jia-Wei, Song, Hui-Ting, Zhou, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379101/
https://www.ncbi.nlm.nih.gov/pubmed/22719322
http://dx.doi.org/10.1107/S1600536812021058
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author Wang, Yang
Mao, Jia-Wei
Song, Hui-Ting
Zhou, Hong
author_facet Wang, Yang
Mao, Jia-Wei
Song, Hui-Ting
Zhou, Hong
author_sort Wang, Yang
collection PubMed
description In the unsymmetrical title complex, [Ni(C(20)H(23)N(4)O(4))]ClO(4), the coordination geometry for the Ni(II) atom can be described as square planar. The aromatic rings in the two ligands are almost vertical, with a dihedral angle of 85.3°. In the crystal, cations and anions are linked by weak C(N)—H⋯O hydrogen bonding.
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spelling pubmed-33791012012-06-20 [2-Formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(II) perchlorate Wang, Yang Mao, Jia-Wei Song, Hui-Ting Zhou, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the unsymmetrical title complex, [Ni(C(20)H(23)N(4)O(4))]ClO(4), the coordination geometry for the Ni(II) atom can be described as square planar. The aromatic rings in the two ligands are almost vertical, with a dihedral angle of 85.3°. In the crystal, cations and anions are linked by weak C(N)—H⋯O hydrogen bonding. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379101/ /pubmed/22719322 http://dx.doi.org/10.1107/S1600536812021058 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yang
Mao, Jia-Wei
Song, Hui-Ting
Zhou, Hong
[2-Formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(II) perchlorate
title [2-Formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(II) perchlorate
title_full [2-Formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(II) perchlorate
title_fullStr [2-Formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(II) perchlorate
title_full_unstemmed [2-Formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(II) perchlorate
title_short [2-Formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(II) perchlorate
title_sort [2-formyl-4-methyl-6-({2-[2-(4-nitro­benzyl­amino)­ethyl­amino]­ethyl­imino}­meth­yl)phenolato]nickel(ii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379101/
https://www.ncbi.nlm.nih.gov/pubmed/22719322
http://dx.doi.org/10.1107/S1600536812021058
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