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Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN (3))dichloridocobalt(II)
In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetracoordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thiadiazole ligands, giving a slightly distorted tetrahedral stereochemistry [bond angle range about Co = 105.16 (12)...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379105/ https://www.ncbi.nlm.nih.gov/pubmed/22719326 http://dx.doi.org/10.1107/S1600536812020995 |
Sumario: | In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetracoordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thiadiazole ligands, giving a slightly distorted tetrahedral stereochemistry [bond angle range about Co = 105.16 (12)–112.50 (10)°]. In the complex, the dihedral angle between the 1,3,4-thiadiazole planes in the two ligands is 72.8 (1)°. There are two intramolecular N—H⋯Cl interactions in the complex unit, while in the crystal, intermolecular N—H⋯N and N—H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011). |
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