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Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN (3))dichloridocobalt(II)
In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetracoordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thiadiazole ligands, giving a slightly distorted tetrahedral stereochemistry [bond angle range about Co = 105.16 (12)...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379105/ https://www.ncbi.nlm.nih.gov/pubmed/22719326 http://dx.doi.org/10.1107/S1600536812020995 |
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author | Song, Ye Ji, Yu-Fei Kang, Min-Yan Liu, Zhi-Liang |
author_facet | Song, Ye Ji, Yu-Fei Kang, Min-Yan Liu, Zhi-Liang |
author_sort | Song, Ye |
collection | PubMed |
description | In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetracoordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thiadiazole ligands, giving a slightly distorted tetrahedral stereochemistry [bond angle range about Co = 105.16 (12)–112.50 (10)°]. In the complex, the dihedral angle between the 1,3,4-thiadiazole planes in the two ligands is 72.8 (1)°. There are two intramolecular N—H⋯Cl interactions in the complex unit, while in the crystal, intermolecular N—H⋯N and N—H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011). |
format | Online Article Text |
id | pubmed-3379105 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791052012-06-20 Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN (3))dichloridocobalt(II) Song, Ye Ji, Yu-Fei Kang, Min-Yan Liu, Zhi-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetracoordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thiadiazole ligands, giving a slightly distorted tetrahedral stereochemistry [bond angle range about Co = 105.16 (12)–112.50 (10)°]. In the complex, the dihedral angle between the 1,3,4-thiadiazole planes in the two ligands is 72.8 (1)°. There are two intramolecular N—H⋯Cl interactions in the complex unit, while in the crystal, intermolecular N—H⋯N and N—H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011). International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379105/ /pubmed/22719326 http://dx.doi.org/10.1107/S1600536812020995 Text en © Song et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Ye Ji, Yu-Fei Kang, Min-Yan Liu, Zhi-Liang Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN (3))dichloridocobalt(II) |
title | Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN
(3))dichloridocobalt(II) |
title_full | Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN
(3))dichloridocobalt(II) |
title_fullStr | Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN
(3))dichloridocobalt(II) |
title_full_unstemmed | Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN
(3))dichloridocobalt(II) |
title_short | Bis(2-amino-5-methyl-1,3,4-thiadiazole-κN
(3))dichloridocobalt(II) |
title_sort | bis(2-amino-5-methyl-1,3,4-thiadiazole-κn
(3))dichloridocobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379105/ https://www.ncbi.nlm.nih.gov/pubmed/22719326 http://dx.doi.org/10.1107/S1600536812020995 |
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