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Bis(2-amino-5-methyl-1,3,4-thia­diazole-κN (3))dichloridocobalt(II)

In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetra­coordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thia­diazole ligands, giving a slightly distorted tetra­hedral stereochemistry [bond angle range about Co = 105.16 (12)...

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Detalles Bibliográficos
Autores principales: Song, Ye, Ji, Yu-Fei, Kang, Min-Yan, Liu, Zhi-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379105/
https://www.ncbi.nlm.nih.gov/pubmed/22719326
http://dx.doi.org/10.1107/S1600536812020995
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author Song, Ye
Ji, Yu-Fei
Kang, Min-Yan
Liu, Zhi-Liang
author_facet Song, Ye
Ji, Yu-Fei
Kang, Min-Yan
Liu, Zhi-Liang
author_sort Song, Ye
collection PubMed
description In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetra­coordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thia­diazole ligands, giving a slightly distorted tetra­hedral stereochemistry [bond angle range about Co = 105.16 (12)–112.50 (10)°]. In the complex, the dihedral angle between the 1,3,4-thia­diazole planes in the two ligands is 72.8 (1)°. There are two intra­molecular N—H⋯Cl inter­actions in the complex unit, while in the crystal, inter­molecular N—H⋯N and N—H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011).
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spelling pubmed-33791052012-06-20 Bis(2-amino-5-methyl-1,3,4-thia­diazole-κN (3))dichloridocobalt(II) Song, Ye Ji, Yu-Fei Kang, Min-Yan Liu, Zhi-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetra­coordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thia­diazole ligands, giving a slightly distorted tetra­hedral stereochemistry [bond angle range about Co = 105.16 (12)–112.50 (10)°]. In the complex, the dihedral angle between the 1,3,4-thia­diazole planes in the two ligands is 72.8 (1)°. There are two intra­molecular N—H⋯Cl inter­actions in the complex unit, while in the crystal, inter­molecular N—H⋯N and N—H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011). International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379105/ /pubmed/22719326 http://dx.doi.org/10.1107/S1600536812020995 Text en © Song et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Ye
Ji, Yu-Fei
Kang, Min-Yan
Liu, Zhi-Liang
Bis(2-amino-5-methyl-1,3,4-thia­diazole-κN (3))dichloridocobalt(II)
title Bis(2-amino-5-methyl-1,3,4-thia­diazole-κN (3))dichloridocobalt(II)
title_full Bis(2-amino-5-methyl-1,3,4-thia­diazole-κN (3))dichloridocobalt(II)
title_fullStr Bis(2-amino-5-methyl-1,3,4-thia­diazole-κN (3))dichloridocobalt(II)
title_full_unstemmed Bis(2-amino-5-methyl-1,3,4-thia­diazole-κN (3))dichloridocobalt(II)
title_short Bis(2-amino-5-methyl-1,3,4-thia­diazole-κN (3))dichloridocobalt(II)
title_sort bis(2-amino-5-methyl-1,3,4-thia­diazole-κn (3))dichloridocobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379105/
https://www.ncbi.nlm.nih.gov/pubmed/22719326
http://dx.doi.org/10.1107/S1600536812020995
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