[4,6-Dimethyl­pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl­phosphane-κP)copper(I)

In the mononuclear title complex, [CuI(C(6)H(8)N(2)S)(C(18)H(15)P)(2)], the Cu(I) ion is in a slightly distorted tetra­hedral coordination geometry formed by two P atoms from two triphenyl­phosphane ligands, one S atom from a 4,6-dimethyl­pyrimidine-2(1H)-thione ligand and one iodide ion. There is a...

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Autores principales: Pakawatchai, Chaveng, Wattanakanjana, Yupa, Choto, Patcharanan, Nimthong, Ruthairat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379106/
https://www.ncbi.nlm.nih.gov/pubmed/22719327
http://dx.doi.org/10.1107/S1600536812021010
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author Pakawatchai, Chaveng
Wattanakanjana, Yupa
Choto, Patcharanan
Nimthong, Ruthairat
author_facet Pakawatchai, Chaveng
Wattanakanjana, Yupa
Choto, Patcharanan
Nimthong, Ruthairat
author_sort Pakawatchai, Chaveng
collection PubMed
description In the mononuclear title complex, [CuI(C(6)H(8)N(2)S)(C(18)H(15)P)(2)], the Cu(I) ion is in a slightly distorted tetra­hedral coordination geometry formed by two P atoms from two triphenyl­phosphane ligands, one S atom from a 4,6-dimethyl­pyrimidine-2(1H)-thione ligand and one iodide ion. There is an intra­molecular N—H⋯I hydrogen bond. In the crystal, π–π stacking inter­actions [centroid–centroid distance = 3.594 (1) Å] are observed.
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spelling pubmed-33791062012-06-20 [4,6-Dimethyl­pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl­phosphane-κP)copper(I) Pakawatchai, Chaveng Wattanakanjana, Yupa Choto, Patcharanan Nimthong, Ruthairat Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [CuI(C(6)H(8)N(2)S)(C(18)H(15)P)(2)], the Cu(I) ion is in a slightly distorted tetra­hedral coordination geometry formed by two P atoms from two triphenyl­phosphane ligands, one S atom from a 4,6-dimethyl­pyrimidine-2(1H)-thione ligand and one iodide ion. There is an intra­molecular N—H⋯I hydrogen bond. In the crystal, π–π stacking inter­actions [centroid–centroid distance = 3.594 (1) Å] are observed. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379106/ /pubmed/22719327 http://dx.doi.org/10.1107/S1600536812021010 Text en © Pakawatchai et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pakawatchai, Chaveng
Wattanakanjana, Yupa
Choto, Patcharanan
Nimthong, Ruthairat
[4,6-Dimethyl­pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl­phosphane-κP)copper(I)
title [4,6-Dimethyl­pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl­phosphane-κP)copper(I)
title_full [4,6-Dimethyl­pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl­phosphane-κP)copper(I)
title_fullStr [4,6-Dimethyl­pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl­phosphane-κP)copper(I)
title_full_unstemmed [4,6-Dimethyl­pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl­phosphane-κP)copper(I)
title_short [4,6-Dimethyl­pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl­phosphane-κP)copper(I)
title_sort [4,6-dimethyl­pyrimidine-2(1h)-thione-κs]iodidobis(triphenyl­phosphane-κp)copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379106/
https://www.ncbi.nlm.nih.gov/pubmed/22719327
http://dx.doi.org/10.1107/S1600536812021010
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