Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate

In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa­hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Jiao, Rui, Qiu, Xiang-Lei, Wang, Jian, Huang, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379109/
https://www.ncbi.nlm.nih.gov/pubmed/22719330
http://dx.doi.org/10.1107/S1600536812021459
Descripción
Sumario:In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa­hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°. In the crystal, the cations, anions and water mol­ecules are linked into a three-dimensional network by C—H⋯Cl, C—H⋯O and O—H⋯Cl hydrogen bonds.

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